Pure rotational spectrum of platinum monoxide (PtO) in the X3Σ0- ground state

被引：12
作者：
Okabayashi, T
Yamazaki, E
Tanimoto, M
机构：
[1] Shizuoka Univ, Ctr Instrumental Anal, Shizuoka 4228529, Japan
[2] Shizuoka Univ, Fac Sci, Dept Chem, Shizuoka 4228529, Japan
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 2005年 / 229卷 / 02期
基金：
日本学术振兴会;
关键词：
D O I：
10.1016/j.jms.2004.09.001
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The microwave spectroscopic study of the platinum monoxide radical PtO generated using a sputtering technique was presented. 15 lines of PtO in the ground vibrational state of the X 3σ 0 - were observed between 205 and 389 GHz. The standard deviations of the fit for each isotopomer were found to be about 10 kHz. It was observed that the rotational constants B 0 give interatomic distances to be about 173.040 pm for all isotopomers.
引用
收藏
页码：283 / 285
页数：3
相关论文
共 14 条
  • [1] RELATIVISTIC EFFECTS IN THE ELECTRONIC-STRUCTURE OF THE MONOXIDES AND MONOCARBONYLS OF NI, PD, AND PT - LOCAL AND GRADIENT-CORRECTED DENSITY-FUNCTIONAL CALCULATIONS
    CHUNG, SC
    KRUGER, S
    PACCHIONI, G
    ROSCH, N
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (09) : 3695 - 3702
  • [2] FOURIER-TRANSFORM EMISSION-SPECTROSCOPY OF THE A'3-PI-X3-EPSILON- TRANSITION OF PTO
    FRUM, CI
    ENGLEMAN, R
    BERNATH, PF
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1991, 150 (02) : 566 - 575
  • [3] OPTICAL-ABSORPTION SPECTRA OF PTO AND PT-2 IN RARE-GAS MATRICES
    JANSSON, K
    SCULLMAN, R
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1976, 61 (02) : 299 - 312
  • [4] RELATIVISTIC EFFECT ON THE INTERATOMIC PLATINUM OXYGEN POTENTIAL AND ITS CONSEQUENCES IN HIGH-ENERGY O2/PT(111) SCATTERING
    KIRCHNER, EJJ
    BAERENDS, EJ
    VANSLOOTEN, U
    KLEYN, AW
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (05) : 3821 - 3830
  • [5] SPECTRUM OF PTO IN 4000-7000 A REGION
    NILSSON, C
    SCULLMAN, R
    MEHENDAL.N
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1970, 35 (02) : 177 - &
  • [6] MILLIMETER AND SUBMILLIMETER-WAVE SPECTROSCOPY OF HNC AND DNC IN THE VIBRATIONALLY EXCITED-STATES
    OKABAYASHI, T
    TANIMOTO, M
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (05) : 3268 - 3271
  • [7] Photoelectron spectroscopy of nickel, palladium, and platinum oxide anions
    Ramond, TM
    Davico, GE
    Hellberg, F
    Svedberg, F
    Salén, P
    Söderqvist, P
    Lineberger, WC
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 2002, 216 (01) : 1 - 14
  • [8] THE EMISSION-SPECTRUM OF PTO BETWEEN 3800-A AND 8900-A
    SASSENBERG, U
    SCULLMAN, R
    [J]. PHYSICA SCRIPTA, 1983, 28 (02) : 139 - 159
  • [9] GROUND-STATE OF PTO
    SASSENBERG, U
    SCULLMAN, R
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1977, 68 (02) : 331 - 332
  • [10] EMISSION-SPECTRUM OF PTO BETWEEN 3800 AND 4500 A
    SCULLMAN, R
    SASSENBERG, U
    NILSSON, C
    [J]. CANADIAN JOURNAL OF PHYSICS, 1975, 53 (19) : 1991 - 1999
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