An enyne metathesis/Diels-Alder reaction sequence towards the synthesis of cup-shaped 5/5/6-tricyclic architectures

被引：19

作者：

Evanno, Laurent ^{[1
]}

Deville, Alexandre ^{[1
]}

Bodo, Bernard ^{[1
]}

Nay, Bastien ^{[1
]}

机构：

[1] CNRS, Museum Natl Hist Nat, Lab Chim & Biochim Substances Nat, F-75005 Paris, France

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 25期

关键词：

enyne metathesis; Diels-Alder cycloaddition; fused tricyclic structure; catalysis; carbonylation;

D O I：

10.1016/j.tetlet.2007.04.107

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A strategy to synthesize the 5/5/6-tricyclic framework of presilphiperfolane natural products is described, involving a model dienyne compound (1). The key steps are an enyne metathesis reaction to introduce the diene part and a Diels-Alder cycloaddition to reveal the tricyclic architecture. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：4331 / 4333

页数：3

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