Highly conductive room temperature molten salts based on small trimethylalkylammonium cations and bis(trifluoromethylsulfonyl)imide

被引：307

作者：

Matsumoto, H ^{[1
]}

Yanagida, M ^{[1
]}

Tanimoto, K ^{[1
]}

Nomura, M ^{[1
]}

Kitagawa, Y ^{[1
]}

Miyazaki, Y ^{[1
]}

机构：

[1] Osaka Natl Res Inst, Dept Energy Convers, Osaka 5638577, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 08期

关键词：

D O I：

10.1246/cl.2000.922

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemically stable and relatively high conductive room temperature molten salts (RTMS) have been obtained with the use of small ammonium cations such as methoxymethyltrimethylammonium and bis(trifluoromethylsulfonyl)imide. The RTMS showed high conductivity (4.7 mS cm(-1) at 25 degrees C) which is the highest value of all the ammonium based RTMS reported so far.

引用

页码：922 / 923

页数：2

共 8 条

[1] Hydrophobic, highly conductive ambient-temperature molten salts [J].

Bonhote, P ;

Dias, AP ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178

[2] NEW AMBIENT-TEMPERATURE MOLTEN-SALT SOLVENT FOR ELECTROCHEMISTRY - TRIETHYL-NORMAL-HEXYLAMMONIUM TRIETHYL-NORMAL-HEXYLBORIDE [J].

FORD, WT .

ANALYTICAL CHEMISTRY, 1975, 47 (07) :1125-1126

[3] The room temperature ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate: Electrochemical couples and physical properties [J].

Fuller, J ;

Carlin, RT ;

Osteryoung, RA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (11) :3881-3886

[4] Acidic 1-ethyl-3-methylimidazolium fluoride: a new room temperature ionic liquid [J].

Hagiwara, R ;

Hirashige, T ;

Tsuda, T ;

Ito, Y .

JOURNAL OF FLUORINE CHEMISTRY, 1999, 99 (01) :1-3

[5] Pyrrolidinium imides: A new family of molten salts and conductive plastic crystal phases [J].

MacFarlane, DR ;

Meakin, P ;

Sun, J ;

Amini, N ;

Forsyth, M .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (20) :4164-4170

[6] The performance and stability of ambient temperature molten salts for solar cell applications [J].

Papageorgiou, N ;

Athanassov, Y ;

Armand, M ;

Bonhote, P ;

Pettersson, H ;

Azam, A ;

Gratzel, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (10) :3099-3108

[7] Synthesis and Properties of Ambient Temperature Molten Salts Based on the Quaternary Ammonium Ion [J].

Sun, Jiazeng ;

MacFarlane, D. R. ;

Forsyth, M. .

IONICS, 1997, 3 (5-6) :356-362

[8] AIR AND WATER STABLE 1-ETHYL-3-METHYLIMIDAZOLIUM BASED IONIC LIQUIDS [J].

WILKES, JS ;

ZAWOROTKO, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (13) :965-967

← 1 →