Recent developments in asymmetric hydroformylation

被引：67

作者：

Chakrabortty, Soumyadeep ^{[1
]}

Almasalma, Ahmad A. ^{[1
]}

de Vries, Johannes G. ^{[1
]}

机构：

[1] Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2021年 / 11卷 / 16期

关键词：

RHODIUM-CATALYZED HYDROFORMYLATION; ANTI-MARKOVNIKOV HYDROFORMYLATION; HIGHLY ENANTIOSELECTIVE HYDROFORMYLATION; AMINOPHOSPHINE PHOSPHINITE LIGANDS; TRANSITION-METAL-COMPLEXES; WIDE-BITE-ANGLE; P-OP LIGANDS; HIGH REGIOSELECTIVITY; BRANCHED ALDEHYDES; ALLYLIC ALCOHOLS;

D O I：

10.1039/d1cy00737h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The recent literature on asymmetric hydroformylation is reviewed from the perspective of the ligand development. Much progress was made in the area of hybrid bidentate ligands containing one P-chiral phosphine and bidentate P-chiral phosphine ligands. A number of other hybrid bidentate ligands were developed and led to very good results. Chiral bisphosphine ligands have also been highly successful. Use of BINOL-based monodentate phosphites and phosphoramidites generally led to lower enantioselectivities. The substrate scope was tremendously expanded and now also includes 1,1-disubsituted alkenes.

引用

页码：5388 / 5411

页数：25

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