Heat Resistance of Ga-Doped ZnO Thin Films for Application as Transparent Electrodes in Liquid Crystal Displays

被引:44
作者
Yamamoto, Naoki [1 ]
Makino, Hisao [1 ]
Yamada, Takahiro [1 ]
Hirashima, Yoshinori [2 ]
Iwaoka, Hiroaki [2 ]
Ito, Takahiro [2 ]
Ujihara, Akira [2 ]
Hokari, Hitoshi [3 ]
Morita, Hidehiro [3 ]
Yamamoto, Tetsuya [1 ]
机构
[1] Kochi Univ Technol, Res Inst, Kochi 7828502, Japan
[2] Geomatec Co Ltd, Ctr Res & Dev, Ota Ku, Tokyo 1460093, Japan
[3] Casio Comp Co Ltd, Elect Device Div, Lab, Tokyo 1928556, Japan
关键词
electrical conductivity; electrodes; gallium; II-VI semiconductors; internal stresses; liquid crystal displays; optical filters; plasma deposition; semiconductor doping; semiconductor thin films; sputter deposition; zinc compounds; ZINC-OXIDE;
D O I
10.1149/1.3267506
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The electrical characteristics and residual stresses in three types of Ga-doped ZnO (GZO) films formed using a reactive plasma deposition system (type 1 film) and a magnetron sputtering system utilizing dc power (type 2 film) or dc+radio-frequency (rf) power (type 3 film) were compared from the viewpoint of heat resistance as a function of the thermal process for liquid crystal display (LCD) fabrication. The resistivity of the as-formed GZO films prepared at 180 degrees C can be ordered as (2.75 mu m)< type 3 film (3.88 mu m)< type 2 film (6.00 mu m). However, the heat resistance of the films was ordered as type 3 (200-250 degrees C)< type 2 (250-300 degrees C)< type 1 (350-400 degrees C). Thus, the GZO films prepared by magnetron sputtering utilizing rf+dc power did not satisfy the condition for transparent electrodes for LCDs in terms of heat resistance against the ca. 250 degrees C processing step. LCD panels (3 in.) using the GZO transparent electrodes on the red-green-blue color filters were fabricated for demonstrating the feasibility of using this material as an electrode.
引用
收藏
页码:J13 / J20
页数:8
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