Pd-Functionalized Carbon Nanotubes for Selective Hydrogenation of 2-Butyne-1,4-diol

被引：7

作者：

Nadgeri, Jayprakash M. ^{[1
]}

Garade, Ajit C. ^{[1
]}

Tambe, Romana A. ^{[2
]}

Gokhale, Suresh P. ^{[2
]}

Rode, Chandrashekhar V. ^{[1
]}

机构：

[1] Natl Chem Lab, Chem Engn & Proc Dev Div, Pune 411008, Maharashtra, India

[2] Natl Chem Lab, Phys & Mat Chem Div, Pune 411008, Maharashtra, India

来源：

ADVANCED SCIENCE LETTERS | 2010年 / 3卷 / 03期

关键词：

HETEROGENEOUS CATALYSIS; NANOFIBERS; OXIDATION; PALLADIUM; STATE; RAMAN;

D O I：

10.1166/asl.2010.1128

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Multiwalled carbon nanotubes were prepared by thermal decomposition method followed by acid treatment and Pd-functionalization with PdCl2 by wet impregnation method. The Pd functionlized carbon nanotubes catalyst was characterized by BET, FT-IR, Raman, XRD, EDX, ICP-OES, SEM and TEM and was evaluated for its activity for hydrogenation of 2-butyne-1,4-diol. It showed higher selectivity (93%) to 2-butene-1,4-diol than Pd supported on commercial carbon (70% selectivity to 2-butene-1,4-diol) for complete conversion of 2-butyne-1,4-diol. The catalyst also exhibited excellent stability as evidenced by the three catalyst recycle experiments.

引用

页码：313 / 318

页数：6

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