Synthesis of ordered arrays of magnesium hydroxide nanoparticles via a simple method

被引:56
作者
An, Dongmin [1 ]
Ding, Xuefeng [1 ]
Wang, Zichen [1 ]
Liu, Yanhua [1 ]
机构
[1] Jilin Univ, Coll Chem, Changchun 130012, Jilin Province, Peoples R China
关键词
Ordered arrays; Magnesium hydroxide; CTAB; Aging; NANORODS; GROWTH; MGO;
D O I
10.1016/j.colsurfa.2009.12.027
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Superfine ordered arrays of magnesium hydroxide (MH) nanoparticles were synthesized via a direct precipitation method at room temperature through aging with cationic surfactant, cetyl trimethyl ammonium bromide ((TAB) as crystal modifying agent. The effect of CTAB on the phase and morphology of MH was investigated by X-ray diffraction (XRD). Fourier transform infrared spectroscopy (FTIR) supported that there was no chemical bond formed between CTAB and MH, and transmission electron microscopy (TEM) indicated that the growing habit of the crystals was altered by the capping effect of CTAB on the surfaces of the crystals. The preferential orientation of the arrays of MH nanoparticles was identified and related process mechanism was discussed. Furthermore, from the results of the thermogravimetric analysis (TGA), it was confirmed that MH particles with different morphologies enhanced the thermal stability of the low density polyethylene (LDPE)/MH composites. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:28 / 31
页数:4
相关论文
共 16 条
  • [1] Alexandre M, 2001, MACROMOL RAPID COMM, V22, P643, DOI 10.1002/1521-3927(20010501)22:8<643::AID-MARC643>3.0.CO
  • [2] 2-#
  • [3] In situ preparation and surface modification of magnesium hydroxide nanoparticles
    An, Dongmin
    Wang, Lili
    Zheng, Yunhui
    Guan, Shuang
    Gao, Xiaoyan
    Tian, Yumei
    Zhang, Hongxi
    Wang, Zichen
    Liu, Yanhua
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 348 (1-3) : 9 - 13
  • [4] Nanoscale magnesium hydroxide and magnesium oxide powders: Control over size, shape, and structure via hydrothermal synthesis
    Ding, Y
    Zhang, GT
    Wu, H
    Hai, B
    Wang, LB
    Qian, YT
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (02) : 435 - 440
  • [5] Morphological study of magnesium hydroxide nanoparticles precipitated in dilute aqueous solution
    Henrist, C
    Mathieu, JP
    Vogels, C
    Rulmont, A
    Cloots, R
    [J]. JOURNAL OF CRYSTAL GROWTH, 2003, 249 (1-2) : 321 - 330
  • [6] Li YD, 2000, ADV MATER, V12, P818, DOI 10.1002/(SICI)1521-4095(200006)12:11<818::AID-ADMA818>3.0.CO
  • [7] 2-L
  • [8] LIEBER CM, 1996, P RA WELCH FDN 40 C
  • [9] Controlled growth of three morphological structures of magnesium hydroxide nanoparticles by wet precipitation method
    Lv, JP
    Qiu, LZ
    Qu, BJ
    [J]. JOURNAL OF CRYSTAL GROWTH, 2004, 267 (3-4) : 676 - 684
  • [10] Magnesium hydroxide dehydroxylation: In situ nanoscale observations of lamellar nucleation and growth
    McKelvy, MJ
    Sharma, R
    Chizmeshya, AVG
    Carpenter, RW
    Streib, K
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (03) : 921 - 926