Determination of alkylphenol ethoxylates in industrial and environmental samples

被引：53

作者：

de Voogt, P ^{[1
]}

de Beer, K ^{[1
]}

van der Wielen, F ^{[1
]}

机构：

[1] Univ Amsterdam, Dept Environm & Toxicol Chem, Amsterdam Res Inst Subst Ecosyst, NL-1018 WV Amsterdam, Netherlands

来源：

TRAC-TRENDS IN ANALYTICAL CHEMISTRY | 1997年 / 16卷 / 10期

关键词：

D O I：

10.1016/S0165-9936(97)00100-3

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Degradation products of nonionic surfactants, which are used in large quantities in several industrial applications, have been shown to elicit estrogenic effects in fire laboratory as well as in the environment. This has prompted the monitoring of such products, in particular the alkylphenols (AP) and alkylphenol ethoxylates (APE), in the environment. This study presents a relatively simple method for the determination of AP and APE in Industrial and environmental samples by HPLC and GC-MS. It discusses some of the inherent analytical issues concomitant with the determination of the complicated mixtures these analytes are composed of. The method was applied to marine and estuarine sediments as well as wastewater and sewage sludge samples taken from industrial plants. In all marine and estuarine samples APE were found with a predominance of of oligomers containing 1-3 ethoxylate units. (C) 1997 Elsevier Science B.V.

引用

页码：584 / 595

页数：12

共 12 条

[1]

BOYER S L, 1977, Environmental Science and Technology, V11, P1167, DOI 10.1021/es60136a001

[2] MONITORING AROMATIC SURFACTANTS AND THEIR BIODEGRADATION INTERMEDIATES IN RAW AND TREATED SEWAGES BY SOLID-PHASE EXTRACTION AND LIQUID-CHROMATOGRAPHY [J].

DICORCIA, A ;

SAMPERI, R ;

MARCOMINI, A .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1994, 28 (05) :850-858

[3]

Falbe J., 1987, SURFACTANTS CONSUMER

[4]

GARTI N, 1987, NONIONIC SURFACTANTS, pCH7

[5]

Holt M. S., 1992, HDB ENV CHEM F, V3, P89

[6] DETERGENT COMPONENTS IN SEWAGE EFFLUENT ARE WEAKLY ESTROGENIC TO FISH - AN IN-VITRO STUDY USING RAINBOW-TROUT (ONCORHYNCHUS-MYKISS) HEPATOCYTES [J].

JOBLING, S ;

SUMPTER, JP .

AQUATIC TOXICOLOGY, 1993, 27 (3-4) :361-372

[7] TRACE ANALYSIS OF ETHOXYLATED NONIONIC SURFACTANTS IN SAMPLES OF INFLUENT AND EFFLUENT OF SEWAGE-TREATMENT PLANTS BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].

KIEWIET, AT ;

VANDERSTEEN, JMD ;

PARSONS, JR .

ANALYTICAL CHEMISTRY, 1995, 67 (23) :4409-4415

[8] Chromatographic tools for analyzing and tracking non-ionic surfactants in the aquatic environment [J].

Kiewiet, AT ;

deVoogt, P .

JOURNAL OF CHROMATOGRAPHY A, 1996, 733 (1-2) :185-192

[9]

KLOSTER G, 1997, SURFACTANT SCI SERIE, V65

[10]

Purdom C.E., 1994, Chemistry and Ecology, V8, P275, DOI 10.1080/02757549408038554

← 1 2 →