Gold(iii) complexes

被引：27

作者：

Blons, Charlie ^{[1
]}

Amgoune, Abderrahmane ^{[1
]}

Bourissou, Didier ^{[1
]}

机构：

[1] Univ Paul Sabatier, CNRS, LHFA, UMR 5069, 118 Route Narbonne, F-31062 Toulouse 09, France

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 31期

关键词：

INTRAMOLECULAR ETA(2)-ARENE; INSERTION; GOLD; COORDINATION; ALKENES; ALKYNES; BOND; FUNCTIONALIZATION; NORBORNADIENE; REACTIVITIES;

D O I：

10.1039/c8dt01457d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrocarbons are widespread ligands and substrates in transition metal chemistry. Although gold(iii) has been known for some time to efficiently activate alkenes and alkynes towards nucleophilic addition, and to readily promote the C-H auration of arenes, the corresponding -complexes have remained elusive until recently. This frontier article highlights recent achievements in the preparation and characterization of gold(iii) complexes. The coordination of alkenes, alkynes and arenes to gold(iii) is presented and discussed.

引用

页码：10388 / 10393

页数：6

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