MnCoP hollow nanocubes as novel electrode material for asymmetric supercapacitors

被引:63
作者
Amiri, Maryam [1 ]
Moosavifard, Seyyed Ebrahim [2 ,3 ]
Davarani, Saied Saeed Hosseiny [1 ]
Kaverlavani, Saeid Kamari [1 ]
Shamsipur, Mojtaba [4 ]
机构
[1] Shahid Beheshti Univ, Fac Chem, GC, Tehran 1983963113, Iran
[2] Jahrom Univ Med Sci, Sch Med, Dept Adv Med Sci & Technol, Jahrom 7414846199, Iran
[3] Jahrom Univ Med Sci, Sch Med, Dept Biochem, Jahrom 7414846199, Iran
[4] Razi Univ, Dept Chem, Kermanshah, Iran
关键词
Metal phosphides; Nanosheet; Hollow nanocubes; Asymmetric supercapacitor; SHAPE-CONTROLLED SYNTHESIS; TEMPLATE SYNTHESIS; PERFORMANCE; NANOSHEETS; NANOBOXES; NANOCAGES; FABRICATION; EFFICIENT; ARRAYS; NANOSTRUCTURES;
D O I
10.1016/j.cej.2021.129910
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Fabrication of novel and efficient electrodes for green and renewable hybrid energy storage systems is an effective approach to deal with energy crisis. In this work, hierarchical nanosheet-based MnCoP hollow nanocubes electrode with the battery type feature has been successfully synthesized by a simple hard and soft acid-base (HSAB) approach followed by a heat treatment. By taking advantage of the remarkable merits including uniform morphology, electrical conductivity, structural stability, large surface area as well as the battery type feature, the nanosheet-based MnCoP hollow nanocubes electrode exhibits enhanced electrochemical performance with high specific capacity of 879C g(-1) at 2 A g(-1) excellent cycling stability of 94.4% capacity retention after 6,000 cycles, and maximum energy and power density of 66.98 Wh Kg(-1) and 16446 W Kg(-1), respectively.
引用
收藏
页数:9
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共 82 条
[41]   Amorphous Ni(OH)2 Nanoboxes: Fast Fabrication and Enhanced Sensing for Glucose [J].
Nai, Jianwei ;
Wang, Shuqian ;
Bai, Yang ;
Guo, Lin .
SMALL, 2013, 9 (18) :3147-3152
[42]   Hexagonal prism arrays constructed using ultrathin porous nanoflakes of carbon doped mixed-valence Co-Mn-Fe phosphides for ultrahigh areal capacitance and remarkable cycling stability [J].
Niu, Richao ;
Wang, Gengjie ;
Ding, Yuying ;
Tang, Shaochun ;
Hu, Xuemin ;
Zhu, Junwu .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (09) :4431-4437
[43]   MOF assistance synthesis of nanoporous double-shelled CuCo2O4 hollow spheres for hybrid supercapacitors [J].
Saleki, Fereshteh ;
Mohammadi, Abdolkhaled ;
Moosavifard, Seyyed Ebrahim ;
Hafizi, Ali ;
Rahimpour, Mohammad Reza .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2019, 556 :83-91
[44]   Highly porous graphitic carbon and Ni2P2O7 for a high performance aqueous hybrid supercapacitor [J].
Senthilkumar, Baskar ;
Khan, Ziyauddin ;
Park, Seungyoung ;
Kim, Kyoungho ;
Ko, Hyunhyub ;
Kim, Youngsik .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (43) :21553-21561
[45]   Facile synthesis of MnPO4•H2O nanosheets/MWCNTs composite as electrode material for high-performance supercapacitors [J].
Sharmila, V ;
Parthibavarman, M. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2019, 30 (22) :19813-19825
[46]   Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction [J].
Shi, Yanmei ;
Zhang, Bin .
CHEMICAL SOCIETY REVIEWS, 2016, 45 (06) :1529-1541
[47]   Synthesis of Cu2O Nanoframes and Nanocages by Selective Oxidative Etching at Room Temperature [J].
Sui, Yongming ;
Fu, Wuyou ;
Zeng, Yi ;
Yang, Haibin ;
Zhang, Yanyan ;
Chen, Hui ;
Li, Yixing ;
Li, Minghui ;
Zou, Guangtian .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (25) :4282-4285
[48]   One-Step Synthesis of 3D Network-like NixCo1-xMoO4 Porous Nanosheets for High Performance Battery-type Hybrid Supercapacitors [J].
Sun, Pengxiao ;
Wang, Chenggang ;
He, Weidong ;
Hou, Peiyu ;
Xu, Xijin .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (11) :10139-10147
[49]   Recent advances in hybrid Cu2O-based heterogeneous nanostructures [J].
Sun, Shaodong .
NANOSCALE, 2015, 7 (25) :10850-10882
[50]   Cu2O-templated strategy for synthesis of definable hollow architectures [J].
Sun, Shaodong ;
Yang, Zhimao .
CHEMICAL COMMUNICATIONS, 2014, 50 (56) :7403-7415