3d-3d-4f Chain Complexes Constructed Using the Dinuclear Metallacyclic Complex [Ni2(mbpb)3]2- [H2mbpb=1,3-Bis(pyridine-2-carboxamide)benzene] as a Ligand: Synthesis, Structures, and Magnetic Properties

被引：19

作者：

Colacio, Enrique ^{[1
]}

Palacios, Maria A. ^{[1
]}

Rodriguez-Dieguez, Antonio ^{[1
]}

Mota, Antonio J. ^{[1
]}

Manuel Herrera, Juan ^{[1
]}

Choquesillo-Lazarte, Duane ^{[2
]}

Clerac, Rodolphe ^{[3
,4
]}

机构：

[1] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain

[2] CSIC, IACT, Lab Estudios Crystalograf, E-18100 Granada, Spain

[3] CNRS, Ctr Rech Paul Pascal, Equipe Mat Mol Magnet, UPR 8641, F-33600 Pessac, France

[4] Univ Bordeaux, UPR 8641, F-33600 Pessac, France

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 04期

关键词：

SINGLE-MOLECULE MAGNETS; GROUND-STATE; BUILDING-BLOCK; SCHIFF-BASE; METAL-IONS; BEHAVIOR; GD; DY; LN; DYNAMICS;

D O I：

10.1021/ic9021867

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of one-dimensional Ni(2)Ln cationic complexes have been prepared by assembling the in situ generated dinuclear mesocate [Ni-2(mbplb)(3)](2-) building block [H(2)mbpb is the ligand 1,3-bis(pyridine-2-carboxamide)benzene] with Ln(3+) metal ions (Ln(3+) = Gd, Tb, Dy). The crystal-field potentials for the two types of site symmetries found for these 3d-3d-4f complexes (LnO(7) and LnO(8)) are quite different, which has a direct influence on the depopulation of the Stark sublevels, the magnetic anisotropy, and the magnetic properties.

引用

页码：1826 / 1833

页数：8

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