Reduced lattice thermal conductivity in Bi-doped Mg2Si0.4Sn0.6

被引:48
作者
Gao, Peng [1 ]
Lu, Xu [2 ]
Berkun, Isil [3 ]
Schmidt, Robert D. [1 ]
Case, Eldon D. [1 ]
Hogan, Timothy P. [1 ,3 ]
机构
[1] Michigan State Univ, Dept Chem Engn & Mat Sci, E Lansing, MI 48824 USA
[2] Michigan State Univ, Dept Phys & Astron, E Lansing, MI 48824 USA
[3] Michigan State Univ, Dept Elect & Comp Engn, E Lansing, MI 48824 USA
关键词
ENHANCED THERMOELECTRIC PROPERTIES;
D O I
10.1063/1.4901178
中图分类号
O59 [应用物理学];
学科分类号
摘要
This letter reports the thermoelectric properties of Bi-doped Mg2Si0.4Sn0.6 thermoelectric materials. It was found that the ZTs of this material could be greatly enhanced by Bi-doping. Analyses on the transport properties showed that the power factors of the material were enhanced while the lattice thermal conductivities were reduced by Bi-doping. The reduction of the lattice thermal conductivity was likely caused by the interstitial Bi impurities. A peak ZT approximate to 1.55 at 773K was obtained. (C) 2014 AIP Publishing LLC.
引用
收藏
页数:5
相关论文
共 22 条
[1]   Electron transport modeling and energy filtering for efficient thermoelectric Mg2Si1-xSnx solid solutions [J].
Bahk, Je-Hyeong ;
Bian, Zhixi ;
Shakouri, Ali .
PHYSICAL REVIEW B, 2014, 89 (07)
[2]  
Berkun I., 2013, MATER RES SOC S P, V1511, P68
[3]   High-performance bulk thermoelectrics with all-scale hierarchical architectures [J].
Biswas, Kanishka ;
He, Jiaqing ;
Blum, Ivan D. ;
Wu, Chun-I ;
Hogan, Timothy P. ;
Seidman, David N. ;
Dravid, Vinayak P. ;
Kanatzidis, Mercouri G. .
NATURE, 2012, 489 (7416) :414-418
[4]   Enhanced thermoelectric properties of Mg2Si0.58Sn0.42 compounds by Bi doping [J].
Du, Zhengliang ;
Zhu, Tiejun ;
Zhao, Xinbing .
MATERIALS LETTERS, 2012, 66 (01) :76-78
[5]   Flux synthesis and thermoelectric properties of eco-friendly Sb doped Mg2Si0.5Sn0.5 solid solutions for energy harvesting [J].
Gao, Hongli ;
Zhu, Tiejun ;
Liu, Xinxin ;
Chen, Luxin ;
Zhao, Xinbing .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (16) :5933-5937
[6]   Transport and Mechanical Properties of High-ZT Mg2.08Si0.4-x Sn0.6Sb x Thermoelectric Materials [J].
Gao, Peng ;
Berkun, Isil ;
Schmidt, Robert D. ;
Luzenski, Matthew F. ;
Lu, Xu ;
Sarac, Patricia Bordon ;
Case, Eldon D. ;
Hogan, Timothy P. .
JOURNAL OF ELECTRONIC MATERIALS, 2014, 43 (06) :1790-1803
[7]   Estimation of the thermal band gap of a semiconductor from Seebeck measurements [J].
Goldsmid, HJ ;
Sharp, JW .
JOURNAL OF ELECTRONIC MATERIALS, 1999, 28 (07) :869-872
[8]   THERMAL CONDUCTIVITY OF ROCK-FORMING MINERALS [J].
HORAI, KI .
JOURNAL OF GEOPHYSICAL RESEARCH, 1971, 76 (05) :1278-&
[9]  
Ioffe A. V., 1956, B ACAD SCI USSR PHYS, V20, p[55, 65]
[10]   Kinetic properties of p-Mg2Si x Sn1-x solid solutions for x < 0.4 [J].
Isachenko, G. N. ;
Zaitsev, V. K. ;
Fedorov, M. I. ;
Burkov, A. T. ;
Gurieva, E. A. ;
Konstantinov, P. P. ;
Vedernikov, M. V. .
PHYSICS OF THE SOLID STATE, 2009, 51 (09) :1796-1799