One-Pot Synthesis of Symmetrical Tertiary and Secondary Amines from Carbonyl Compounds, Ammonium Carbonate and Carbon Monoxide as a Reductant

被引：4

作者：

Muratov, Karim ^{[1
]}

Afanasyev, Oleg, I ^{[1
]}

Kuchuk, Ekaterina ^{[1
]}

Runikhina, Sofiya ^{[1
]}

Chusov, Denis ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Vavilova St 28, Moscow 119991, Russia

[2] GV Plekhanov Russian Univ Econ, 36 Stremyanny Per, Moscow 117997, Russia

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 2019卷 / 38期

基金：

俄罗斯科学基金会;

关键词：

Aldehydes; Ketones; Tertiary amines; Secondary amines; Carbon monoxide; RUTHENIUM-CATALYZED SYNTHESIS; N-ALKYLATION; UNACTIVATED OLEFINS; ALCOHOLS; HYDROAMINOMETHYLATION; TRIBENZYLAMINE; HYDROAMINATION; COMPLEX;

D O I：

10.1002/ejoc.201901175

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rh-catalyzed one-step synthesis of tertiary and secondary amines from aldehydes and ketones, ammonium carbonate serving as nitrogen source, and carbon monoxide as a reducing agent has been developed. Aliphatic and aromatic aldehydes lead to the corresponding tertiary symmetrical amines in 69-83 % yields. Aromatic and aliphatic ketones lead to the corresponding secondary symmetrical amines which were obtained in 62-79 % yields.

引用

页码：6557 / 6560

页数：4

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