Recent advances in selective C-C bond coupling for ethanol upgrading over balanced Lewis acid-base catalysts

被引：27
作者：
Dai, Jingjing [1 ,2 ]
Zhang, Hongbo [1 ,2 ]
机构：
[1] Nankai Univ, Sch Mat Sci & Engn, Tianjin 300350, Peoples R China
[2] Nankai Univ, Natl Inst Adv Mat, Tianjin 300350, Peoples R China
来源：
SCIENCE CHINA-MATERIALS | 2019年 / 62卷 / 11期
关键词：
balanced Lewis acid-base pair; aldol condensation; ethanol upgrading; C-C bond formation; metal oxide; METAL-ORGANIC FRAMEWORK; ALDOL CONDENSATION; MIXED-OXIDES; CASCADE REACTIONS; BIO-ETHANOL; N-BUTANOL; ACETALDEHYDE; CONVERSION; 1,3-BUTADIENE; BUTADIENE;
D O I：
10.1007/s40843-019-9454-x
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Ethanol is a considerable platform molecule in biomass conversion, which could be acquired in quantity through acetone-butanol-ethanol (ABE) fermentation. People have been working on the upgrading of ethanol to value added chemicals for decades. In the meantime, 1-butanol and a series of value added products have been selectively generated through C-C bond coupling. In this mini-review, we focus on the recent advances in selective C-C bond formation over balanced Lewis acid-base catalysts such as modified metal oxide, mixed metal oxide, hydroxyapatite and zeolite confined transition metal oxide catalysts. Among them, Pd-MgAlOx and Sr-based hydroxyapatite exhibit >70% 1-butanol selectivity, while ZnxZryOz and Ta-SiBEA zeolite achieve >80% of isobutene and butadiene selectivity respectively. The mechanism and reaction pathway of C-C bond formation in each reaction system are described in detail. The correlation between C-C bond coupling and the acidity/basicity of the Lewis acid-base pairs from the surface of the catalysts are also discussed.
引用
收藏
页码：1642 / 1654
页数：13
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