Enhanced luminescence by charge compensation in red-emitting Eu3+-activated Ca3Sr3(VO4)4

被引:28
作者
Choi, Sungho [1 ]
Moon, Young-Min [1 ]
Jung, Ha-Kyun [1 ]
机构
[1] Korea Res Inst Chem Technol, Device Mat Res Ctr, Taejon 305600, South Korea
关键词
Ceramics; X-ray diffraction; Luminescence; Optical properties;
D O I
10.1016/j.materresbull.2009.09.035
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effects of charge compensation on the luminescence behavior of a red-emitting phosphor, Ca3Sr3(VO4)(4):Eu3+, were investigated. It has been observed that charge compensated by monovalent ions, especially Na+, shows greatly enhanced red emission under ultraviolet excitation. It is found that Na2CO3 addition acts as a fluxing agent and plays a role in charge compensation, which clearly improves the emission intensity of Eu3+-activated Ca3Sr3(VO4)(4). Enhanced emission intensity of the corresponding charge compensated phosphors under ultraviolet radiation may find application in the production of red phosphors for white light-emitting diodes. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:118 / 120
页数:3
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