The effect of torrefaction pre-treatment on the pyrolysis of corn cobs

被引:57
作者
Klaas, Matt [1 ]
Greenhalf, Charles [1 ,2 ]
Ouadi, Miloud [2 ]
Jahangiri, Hessam [2 ]
Hornung, Andreas [2 ,3 ,4 ]
Briens, Cedric [1 ]
Berruti, Franco [1 ]
机构
[1] Univ Western Ontario, Inst Chem & Fuels Alternat Resources ICFAR, Dept Chem & Biochem Engn, London, England
[2] Univ Birmingham, Sch Chem Engn, Birmingham B15 2TT, W Midlands, England
[3] Fraunhofer Inst Environm Safety & Energy Technol, Maxhutte 1, D-92237 Sulzbach Rosenberg, Germany
[4] Friedrich Alexander Univ Erlangen Nuremberg, Schlosspl 4, D-91054 Erlangen, Germany
关键词
Corn cobs; Pyrolysis; Torrefaction; Grinding energy; Bio-oil; ACETIC-ACID KETONIZATION; DE-INKING SLUDGE; BIO-OIL; HYDROTHERMAL LIQUEFACTION; INTERMEDIATE PYROLYSIS; BIOMASS; TEMPERATURE; SOFTWOOD; CATALYST; STOVER;
D O I
10.1016/j.rineng.2020.100165
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Production of green fuels and chemicals from non-edible corn cob residues presents an excellent opportunity to produce sustainable low carbon energy vectors as an alternative to fossil fuels. The objective of this study was to optimize the fuel physical and chemical properties of torrefied corn cobs bio-oil by investigating the relationship between feedstock pre-treatment (torrefaction) temperatures (240, 260, 280 and 300 degrees C), and subsequent pyrolysis temperatures (400, 450, 500 and 550 degrees C). This experimental methodology aimed to improve both yields and properties of bio-oils from corn cobs. Torrefaction was first carried out as a pre-treatment step using a custom-built torrefaction reactor followed by pyrolysis using a continuous fluidized bed reactor. Torrefaction was found to be a promising pre-treatment step because it had the effect of reducing the water content and viscosity within the bio-oil. Corn cobs grinding energy requirements could be reduced by 69% when torrefaction was applied from 240 degrees C to 260 degrees C. A maximum bio-oil yield of 51.7% was achieved when the optimal temperatures (torrefaction 260 degrees C and pyrolysis 450 degrees C) was applied. Overall, using torrefaction as a pre-treatment step before pyrolysis was shown to be a promising approach for improving some physiochemical properties of bio-oil for its application as a fuel.
引用
收藏
页数:7
相关论文
共 53 条
[1]  
Albaladejo-Hernandez D., 2020, RESULTS ENG, V5
[2]   Alterations in energy properties of eucalyptus wood and bark subjected to torrefaction: The potential of mass loss as a synthetic indicator [J].
Almeida, G. ;
Brito, J. O. ;
Perre, P. .
BIORESOURCE TECHNOLOGY, 2010, 101 (24) :9778-9784
[3]   Influence of torrefaction on the grindability and reactivity of woody biomass [J].
Arias, B. ;
Pevida, C. ;
Fermoso, J. ;
Plaza, M. G. ;
Rubiera, F. ;
Pis, J. J. .
FUEL PROCESSING TECHNOLOGY, 2008, 89 (02) :169-175
[4]  
Bergman P.C., 2005, TORREFACTION ENTRAIN, P78
[5]  
Bergman P.C., 2005, TORREFACTION BIOMASS
[6]   Optimization of an Intermittent Slug Injection System for Sawdust Biomass Pyrolysis [J].
Berruti, Federico M. ;
Ferrante, Lorenzo ;
Berruti, Franco ;
Briens, Cedric .
INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING, 2009, 7
[7]   Fast pyrolysis of biomass thermally pretreated by torrefaction [J].
Boateng, A. A. ;
Mullen, C. A. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2013, 100 :95-102
[8]   Bio-oils obtained by vacuum pyrolysis of softwood bark as a liquid fuel for gas turbines. Part I: Properties of bio-oil and its blends with methanol and a pyrolytic aqueous phase [J].
Boucher, ME ;
Chaala, A ;
Roy, C .
BIOMASS & BIOENERGY, 2000, 19 (05) :337-350
[9]   Review of fast pyrolysis of biomass and product upgrading [J].
Bridgwater, A. V. .
BIOMASS & BIOENERGY, 2012, 38 :68-94
[10]   Upgrading Biomass Fast Pyrolysis Liquids [J].
Bridgwater, Anthony V. .
ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, 2012, 31 (02) :261-268