Synthesis of reactive microgels by emulsion copolymerization of methyl vinyl ketone with styrene and their reactivity

被引：0

作者：

Park, SW ^{[1
]}

Kim, JS

机构：

[1] Chungnam Natl Univ, Dept Polymer Sci & Engn, Taejon 305764, South Korea

[2] Kumho Petrochem Co Ltd, Ulsan, South Korea

来源：

POLYMER-KOREA | 1998年 / 22卷 / 01期

关键词：

poly(methyl vinyl ketone); reactive microgel; particle viscosity; hexamethylene-diamine;

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Homopolymers of methyl vinyl ketone and its copolymers with styrene were prepared by the emulsion polymerization using divinylbenzene as a crosslinking agent. The quantitative effect of styrene and divinylbenzene on the colloidal Stability, degree of crosslinking, and swelling ratio was investigated by measuring density and viscosity. The viscosities of latex particles decrease drastically with increase of crosslinking agent and content of styrene. The reactivity of particles was analyzed by the product with hexamethylenediamine, of which -C=N- bonds were mostly observed in the condensation reaction between carbonyl and amino groups. The stability of the emulsion particles was maintained even after the reaction and the extent of reactions decreased with the crosslinker.

引用

页码：15 / 22

页数：8