An experimental investigation into the foaming tendency of diethanolamine gas sweetening solutions

被引:16
作者
McCarthy, J
Trebble, MA
机构
[1] Alberta Nat Gas Co Ltd, Calgary, AB T2P 4L7, Canada
[2] Univ Calgary, Dept Chem & Petr Engn, Calgary, AB T2N 1N4, Canada
关键词
amine; foaming; diethanolamine; DEA; sweetening; ethane; nitrogen; high pressure;
D O I
10.1080/00986449608936451
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The foaming tendency of a 30 weight % solution of diethanolamine (DEA) in distilled water was measured over a temperature range of 20-85 degrees C and a pressure range of .1-3 MPa in the presense of a number of contaminants including carboxylic acids, oils, 1-4 bis (2-hydroxyethyl) piperazine (HEP), methanol, iron sulphide, silicone antifoam, etc. The measurements were conducted using a Jerguson high pressure sight glass contained in an air bath. Foaming was measured at gas rates up to 7.5 standard m(3)/d using air, nitrogen, carbon dioxide, and ethane. One notable observation was that the addition of most of the contaminants commonly identified as foam promoters did not create a foaming system with a clean 30% DEA solution. In fact, the only solutes that produced significant foaming were the carboxylic acids as noted previously in the literature by Pauley et al. (1989). The addition of contaminants to a foaming system did increase foam heights and stability substantially and results are presented for methanol and HEP addition to a foaming system of DEA-carboxylic acid. The effects of temperature, pressure, and gas flow rates on foam heights and foam break times were measured for a number of systems. Foaming was increased by a higher temperature and by higher pressure and was much more pronounced when carbon dioxide or ethane gases were used.
引用
收藏
页码:159 / 171
页数:13
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