Crevice Corrosion Resistance and Structure of Passive Film on Fe-Mn-Si-Cr-Ni Steel

被引：2

作者：

Nishimura, Toshiyasu ^{[1
]}

机构：

[1] Natl Inst Mat Sci, 1-2-1 Sengen, Tsukuba, Ibaraki 3050047, Japan

来源：

ISIJ INTERNATIONAL | 2016年 / 56卷 / 04期

关键词：

shape memory alloy; crevice corrosion; transmission electron microscopy; SHAPE-MEMORY ALLOY; WET/DRY ENVIRONMENT; CARBON-STEEL; BEHAVIOR; TRANSFORMATION; OXIDES;

D O I：

10.2355/isijinternational.ISIJINT-2015-634

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The crevice corrosion resistance of an Fe-Mn-Si-Cr-Ni (15 Mn) steel as a shape memory alloy was estimated by laser microscopy and statistical calculation of the corrosion depth, and the structure of the passive film formed on the steel was examined by EELS (Electron Energy Loss Spectroscopy) analysis using TEM (transmission electron microscopy). The crevice corrosion results were analyzed using a Gumbel distribution, and the mode (lambda) and distribution parameter (alpha) of the maximum corrosion depth of the 15 Mn steel were found to be much smaller than those of 430 stainless steel (SUS: 16Cr - Fe). This shows that 15 Mn steel has a higher crevice corrosion resistance than 430 SUS steel. In AES and XPS analysis, the passive film of 15 Mn steel was shown to contain Fe, Mn, Cr, Si and Ni. From TEM-EELS, the passive film was found to consist of 2 layers. In the passive film, Cr and Si are thought to be effective early, with Ni preventing penetration of crevice corrosion. It was found that 15 Mn steel could maintain a passive film which was composed of effective elements in a crevice corrosion environment.

引用

页码：654 / 660

页数：7

共 24 条

[11] EFFECTS OF ALLOYING ADDITIONS ON FE-MN-SI SHAPE MEMORY ALLOYS [J].

OTSUKA, H ;

YAMADA, H ;

MARUYAMA, T ;

TANAHASHI, H ;

MATSUDA, S ;

MURAKAMI, M .

ISIJ INTERNATIONAL, 1990, 30 (08) :674-679

[12] SUCCESSIVE STRESS-INDUCED MARTENSITIC TRANSFORMATIONS AND ASSOCIATED TRANSFORMATION PSEUDOELASTICITY IN CU-AL-NI ALLOYS [J].

OTSUKA, K ;

SAKAMOTO, H ;

SHIMIZU, K .

ACTA METALLURGICA, 1979, 27 (04) :585-601

[13] Study of mixed flowing gas exposure of copper [J].

Reid, M. ;

Punch, J. ;

Garfias-Mesias, L. F. ;

Shannon, K. ;

Belochapkine, S. ;

Tanner, D. A. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (04) :C147-C153

[14] Corrosion resistance of copper-coated contacts [J].

Reid, M. ;

Punch, J. ;

Grace, G. ;

Garfias, L. F. ;

Belochapkine, S. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (12) :B513-B517

[15] Investigation into the evolution of corrosion product layer (CPL) of 1018 C-steel exposed to multiphase environment using FIB and EIS techniques [J].

Sapre, K ;

Seal, S ;

Jepson, P ;

Wang, HB ;

Rahman, Z ;

Smith, T .

CORROSION SCIENCE, 2003, 45 (01) :59-80

[16] SHAPE MEMORY EFFECT IN GAMMA REVERSIBLE EPSILON TRANSFORMATION IN FE-30MN-1SI ALLOY SINGLE-CRYSTALS [J].

SATO, A ;

CHISHIMA, E ;

SOMA, K ;

MORI, T .

ACTA METALLURGICA, 1982, 30 (06) :1177-1183

[17] DEVELOPMENT OF A SHAPE MEMORY ALLOY FE-MN-SI [J].

SATO, A ;

MORI, T .

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1991, 146 (1-2) :197-204

[18]

SAWAGCHI T, 2015, B IRON STEEL I JPN, V20, P96

[19] Influence of dichromate ions on corrosion processes on pure magnesium [J].

Schmutz, P ;

Guillaumin, V ;

Lillard, RS ;

Lillard, JA ;

Frankel, GS .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (04) :B99-B110

[20] EVALUATION OF CORROSION FAILURE BY EXTREME VALUE STATISTICS [J].

SHIBATA, T .

ISIJ INTERNATIONAL, 1991, 31 (02) :115-121

← 1 2 3 →