Co-precipitation synthesis and luminescence properties of K2TiF6:Mn4+ red phosphors for warm white light-emitting diodes

被引:30
作者
Liao, Jinsheng [1 ]
Nie, Liling [1 ]
Zhong, Laifu [1 ]
Gu, Qingjie [1 ]
Wang, Qi [1 ]
机构
[1] Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
XRD; co-precipitation; photoluminescence; phosphor; PHOTOLUMINESCENCE PROPERTIES; LED APPLICATIONS; MECHANISM; TRANSITIONS; SPECTRA; RATIO;
D O I
10.1002/bio.3026
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
K2TiF6:Mn4+ red phosphors with different Mn4+ doping concentrations were obtained using the co-precipitation method. X-Ray diffraction, scanning electron microscopy, Raman spectra, Fourier transform infrared spectroscopy, photoluminescence excitation and emission spectra and decay curves were used to characterize the properties of K2TiF6:Mn4+ phosphors. Under excitation at 470 nm, an intense red emission peak around 631 nm corresponding to the E-2(g)-(4)A(2) transition of Mn4+ was observed for 2.48 mol% K2TiF6:Mn4+ phosphors and was used as the optimum doping concentration. The excellent luminescent properties of K2TiF6:Mn4+ suggest that this material might be a promising red phosphor for generating warm white light in phosphor-converted white light-emitting diodes. Copyright (c) 2015 John Wiley & Sons, Ltd.
引用
收藏
页码:802 / 807
页数:6
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