4He thermophysical properties:: New ab initio calculations

被引:87
作者
Hurly, John J. [1 ]
Mehl, James B.
机构
[1] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA
[2] KT Consulting Inc, Orcas, WA 98280 USA
关键词
helium; second virial; theoretical interatomic potential; thermal conductivity; thermophysical standards; transport properties; viscosity; CORRELATED GAUSSIAN FUNCTIONS; HELIUM DIMER; TRANSPORT-PROPERTIES; CROSS-SECTIONS; ADIABATIC APPROXIMATION; DISPERSION COEFFICIENTS; HIGH-ACCURACY; PHASE-SHIFTS; VALUES; GASES;
D O I
10.6028/jres.112.006
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Since 2000, atomic physicists have reduced the uncertainty of the helium-helium "ab initio" potential; for example, from approximately 0.6% to 0.1% at 4 bohr, and from 0.8% to 0.1% at 5.6 bohr. These results led us to: ( 1) construct a new interatomic potential phi(07), ( 2) recalculate values of the second virial coefficient, the viscosity, and the thermal conductivity of He-4 from 1 K to 10,000 K, and ( 3), analyze the uncertainties of the thermophysical properties that propagate from the uncertainty of phi(07) and from the Born-Oppenheimer approximation of the electron-nucleon quantum mechanical system. We correct minor errors in a previous publication [ J. J. Hurly and M. R. Moldover, J. Res. Nat. Inst. Standards Technol. 105, 667 ( 2000)] and compare our results with selected data published after 2000. The ab initio results tabulated here can serve as standards for the measurement of thermophysical properties.
引用
收藏
页码:75 / 94
页数:20
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