Cu-catalyzed intramolecular aryl-etherification reactions of alkoxyl alkynes with diaryliodonium salts via cleavage of a stable C-O bond

被引：43

作者：

Chen, Jing ^{[1
,2
]}

Chen, Chao ^{[1
]}

Chen, Junjie ^{[1
]}

Wang, Guohua ^{[1
]}

Qu, Hongmei ^{[2
]}

机构：

[1] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China

[2] Tianjin Univ, Sch Chem Engn & Technol, Dept Pharmaceut Engn, Key Lab Syst Bioengn,Minist Educ, Tianjin 300072, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 07期

基金：

中国国家自然科学基金;

关键词：

METAL-FREE SYNTHESIS; ONE-POT SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; CASCADE ANNULATION; TETRAHYDROFURANS; CARBOETHERIFICATION; HETEROCYCLES; DERIVATIVES; ALKENES; ACETOGENINS;

D O I：

10.1039/c4cc08363f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel Cu-catalyzed intramolecular aryl-etherification reaction of alkoxyl alkynes with diaryliodonium salts is realized. The reactions proceed smoothly to produce valuable oxo-heterocycles with readily available linear starting materials via cleavage of a stable C-O bond.

引用

页码：1356 / 1359

页数：4

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