Synthesis and characterization of novel intramolecularly base-stabilized BEt2 and BEt derivatives:: molecular structures of 1-Et2BOCPh2-2-NMe2C6H4, 1-(CH3COO)EtBOCCy2-2-NMe2C6H4 and BEt(1-OCPh2CH2-2-NMe2C6H4)2

被引：10

作者：

Al-Masri, HT

Sieler, J

Junk, PC

Domasevitch, KV

Hey-Hawkins, E ^{[1
]}

机构：

[1] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany

[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[3] Natl Taras Shevchenko Univ Kiev, Dept Inorgan Chem, Kiev, Ukraine

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 02期

关键词：

boranes; ethylboranes; boronalkoxides; crystal structure;

D O I：

10.1016/j.jorganchem.2004.09.071

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of BEt3 with the (2-dimethylaminophenyl)alcohols 1-HOX-2-NMe2C6H4 [X = CPh2 (1), CCy2 (2), CPh2CH2 (3)] [1:1 (for 1-3) or 1:2 (for 3)] in the presence of 'BuCO2H as catalyst gave the BEt2 or BEt derivatives 1-Et2BOX-(2)-NMe2C6H4 [X = CPh2 (4), CCy2 (5), CPh2CH2 (7)] and BEt(1 -OCPh2CH2-2-NMe2C6H4)(2) (8). Treatment of 5 with acetic acid gave 1-(CH3COO)EtBOCCy2-2-NMe2C6H4 (6). Compounds 4-8 were characterized spectroscopically (NMR, IR, MS). Crystal structure determinations were carried out on 4, 6 and 8. For the chiral compound 6, both enantiomers are present in the unit cell. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：469 / 476

页数：8

共 50 条

[1] Bipy, phen, and P(C6H4CH2NMe2-2)3 in the synthesis of cationic silver(I) complexes;: the solid-state structures of [P(C6H4CH2NMe2-2)3]AgOTf and [Ag(phen)2]OTf
Leschke, M
Rheinwald, G
Lang, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (11): : 2470 - 2477
[2] THE REACTION OF R,S AND R,R/S,S-[FE-2(ETA,ETA-C5H4CH(NME(2))CH(NME(2))C5H4)(CO)(2)(MU-CO)(2)] AND [FE-2(ETA,ETA-C5H4CH2CH(NME(2))C5H4)(CO)(2)(MU-CO)(2)] WITH ALKYLATING-AGENTS - PREPARATION, STRUCTURE AND SPECTRA OF [FE-2(ETA,ETA-C5H4CH(NME(2))CH(NME(3))C5H4)(CO)(2)(MU-CO)(2)](+) AND [FE-2(ETA,ETA-C5H4CH2CH(NME(3))C5H4)(CO)(2)(MU-CO)(2)](+) SALTS
COX, MG
MANNING, AR
SOYE, P
MCARDLE, P
CUNNINGHAM, D
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 484 (1-2) : 97 - 106
[3] Synthesis, structural, characterization and Hirshfeld analysis of a bisselenide and a zinc complex of a new hemilabile ferrocenylbisphosphane, [Fe{C5H4P(C6H4CH2NMe2-o)2}2]
Kunchur, Harish S.
Mondal, Dipanjan
Rao, Sowmya
Mague, Joel T.
Balakrishna, Maravanji S.
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2021, 77 : 725 - +
[4] Reaction of C(NMe2)4 with Ni(CO)4 -: Syntheses and structures of [C(NMe2)3][(CO)3NiC(O)NMe2], [C(NMe2)3]2[Ni5(CO)12], and [C(NMe2)3]3[Ni6(CO)12][O2CNMe2]
Petz, W
Neumüller, B
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (09): : 2274 - 2280
[5] Synthesis and crystal structure of cluster [C6H4-1,2(CO2CH2C2H-μ)2][Co2(CO)6]2
Chen, XN
Zhang, J
Yin, YQ
Sun, J
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 18 (04) : 249 - 253
[6] Synthesis, structural characterization and Hirshfeld surface analysis of copper(I) complexes containing hemilabile-ferrocenylbisphosphine [Fe{C5H4P(C6H4CH2NMe2-o)2}2]
Mondal, Dipanjan
Rao, Sowmya
Mague, Joel
Balakrishna, Maravanji S.
INDIAN JOURNAL OF CHEMISTRY, 2023, 62 (10): : 1081 - 1090
[7] Synthesis and characterization of 1,3,2-bis (arylamino) phospholidine, 2-oxide derivatives:: Crystal structures of Cl(O)PN(p-Me-C6H4 CH2CH2N(p-Me-C6H4) and ((CH2C6H5)(CH3)N)(O)PN(p-Me-C6H4)CH2CH2N(p-Me-C6H4)
Gholivand, K
Mojahed, F
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (10): : 1912 - 1918
[8] Synthesis and Crystal Structure of Cluster 〔C6H4-1,2-（CO2CH2C2H-μ）2〕〔Co2（CO）6〕2
CHEN XueNian ZHANG Jie YIN YuanQi (State Key Laboratory for Oxo Synthesis and Selective Oxidation
结构化学, 1999, (04) : 13 - 17
[9] Syntheses and crystal structures of [(C6H5CH2C5H4)(2)GdCl center dot THF](2) and (C6H5CH2C5H4)(2)ErCl center dot THF
Xia, JS
Jin, ZS
Chen, WQ
CHINESE JOURNAL OF CHEMISTRY, 1996, 14 (01) : 31 - 39
[10] Novel zirconium complexes derived from C-2-symmetric diamide ligands; The X-ray crystal structure of [Zr(eta(1)-CH(2)Ph)(eta(2)-CH(2)Ph){(C6H3)(2)-2,2'-(NCH(2)C(6)H(4)Ph-4)(2)-6,6'-Me(2)}]
Cloke, FGN
Geldbach, TJ
Hitchcock, PB
Love, JB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 506 (1-2) : 343 - 345

← 1 2 3 4 5 →