Superconductivity at 14.2 K in layered organics under extreme pressure

被引:160
作者
Taniguchi, H
Miyashita, M
Uchiyama, K
Satoh, K
Môri, N
Okamoto, H
Miyagawa, K
Kanoda, K
Hedo, M
Uwatoko, Y
机构
[1] Saitama Univ, Fac Sci, Dept Phys, Saitama 3388570, Japan
[2] Kanazawa Univ, Fac Med, Kanazawa, Ishikawa 9200942, Japan
[3] Univ Tokyo, Dept Appl Phys, Bunkyo Ku, Tokyo 1138656, Japan
[4] Univ Tokyo, Inst Solid State Phys, Chiba 2778581, Japan
关键词
beta '-(BEDT-TTF)2ICl(2); organic superconductor; superconducting transition temperature; high pressure; cubic anvil press; phase diagram;
D O I
10.1143/JPSJ.72.468
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We demonstrate that an organic Mott insulator, beta'-(BEDT-TTF)(2)ICl2, is metallized by application of extremely high pressure by means of the cubic anvil press. When the metallic state is stabilized, superconductivity with the highest transition-temperature (T-3) among the organic systems appears. The lower limit of the pressure at which the superconducting transition manifests itself is approximately 7.0 GPa and T-c reaches a maximum value, 14.2 K (onset), at 8.2 GPa. The pressure-temperature phase diagram is constructed and discussed in terms of the comparison with those of other organic systems,
引用
收藏
页码:468 / 471
页数:4
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