Energy efficient thermochemical conversion of very wet biomass to biofuels by integration of steam drying, steam electrolysis and gasification

被引:26
作者
Clausen, Lasse R. [1 ]
机构
[1] Tech Univ Denmark, Sect Thermal Energy, Dept Mech Engn, Nils Koppels Alle Bld 403, DK-2800 Lyngby, Denmark
关键词
Steam drying; Gasification; Electrolysis; SOEC; Synthetic natural gas; Thermodynamic analysis; SOLID OXIDE ELECTROLYSIS; ENHANCED BIOMASS; HYDROGEN;
D O I
10.1016/j.energy.2017.02.132
中图分类号
O414.1 [热力学];
学科分类号
摘要
A novel system concept is presented for the thermochemical conversion of very wet biomasses such as sewage sludge and manure. The system integrates steam drying, solid oxide electrolysis cells (SOEC) and gasification for the production of synthetic natural gas (SNG). The system is analyzed by thermodynamic modelling and the analysis shows that the system can handle mechanically dried biomasses with a water content of 70 wt% and an ash content of up to 50 wt% (dry basis). A high tolerable ash content is an advantage because very wet biomasses, such as sewage sludge and manure, have a high ash content. The analysis shows that the total efficiency of the novel system is 69-70% depending on the biomass ash content, while the biomass to SNG energy ratio is 165%, which is near the theoretical maximum because electrolytic hydrogen is supplied to the synthesis gas. It is proposed to combine the novel system with an anaerobic digester for conversion of biomasses with high nitrogen content, such as sewage sludge. The organic nitrogen in the sewage sludge will be mineralized in the digester instead of ending up as N-2 in the SNG product. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:327 / 336
页数:10
相关论文
共 25 条
[1]   Validation of a continuous combined heat and power (CHP) operation of a two-stage biomass gasifier [J].
Ahrenfeldt, Jesper ;
Henriksen, Ulrik ;
Jensen, Torben K. ;
Gobel, Benny ;
Wiese, Lars ;
Kather, Alphons ;
Egsgaard, Helge .
ENERGY & FUELS, 2006, 20 (06) :2672-2680
[2]  
[Anonymous], 2012, EVID BASED COMPLEMEN
[3]  
Bejan A, 1996, Thermal Design and Optimization
[4]  
Bentzen J, 2004, P 2 WORLD C TECHN EX, P10
[5]   Sustainability Assessment of an Integrated High Temperature Steam Electrolysis-Enhanced Biomass to Liquid Fuel Process [J].
Bernical, Quentin ;
Joulia, Xavier ;
Noirot-Le Borgne, Isabelle ;
Floquet, Pascal ;
Baurens, Pierre ;
Boissonnet, Guillaume .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (22) :7189-7195
[6]   Maximizing biofuel production in a thermochemical biorefinery by adding electrolytic hydrogen and by integrating torrefaction with entrained flow gasification [J].
Clausen, Lasse R. .
ENERGY, 2015, 85 :94-104
[7]   Thermodynamic analysis of small-scale dimethyl ether (DME) and methanol plants based on the efficient two-stage gasifier [J].
Clausen, Lasse R. ;
Elmegaard, Brian ;
Ahrenfeldt, Jesper ;
Henriksen, Ulrik .
ENERGY, 2011, 36 (10) :5805-5814
[8]   Technoeconomic analysis of a methanol plant based on gasification of biomass and electrolysis of water [J].
Clausen, Lasse R. ;
Houbak, Niels ;
Elmegaard, Brian .
ENERGY, 2010, 35 (05) :2338-2347
[9]   Biomass integrated gasification-SOFC systems: Technology overview [J].
Din, Zia Ud ;
Zainal, Z. A. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2016, 53 :1356-1376
[10]   Process design of Synthetic Natural Gas (SNG) production using wood gasification [J].
Duret, A ;
Friedli, C ;
Maréchal, F .
JOURNAL OF CLEANER PRODUCTION, 2005, 13 (15) :1434-1446