Kinetic Evaluation of the Charge Migration and H2O2 Transport Rates During the Electrocatalytic Reduction of H2O2 on Thin Prussian Blue Films

被引：1
|
作者：
Resetar, Egon [1 ]
Cicic, Sandra [1 ]
Ivekovic, Damir [1 ]
机构：
[1] Univ Zagreb, Fac Food Technol & Biotechnol, Dept Chem & Biochem, Lab Gen & Inorgan Chem & Electroanal, Pierottijeva 6, HR-10000 Zagreb, Croatia
来源：
CROATICA CHEMICA ACTA | 2019年 / 92卷 / 03期
关键词：
iron(III) hexacyanoferrate(II); Prussian blue; electron transport; H2O2; diffusion; electrocatalysis; kinetics; HYDROGEN-PEROXIDE; ELECTROCHEMICAL REACTIONS; SENSITIVITY; ELECTRODES; CATALYSIS; SENSOR;
D O I：
10.5562/cca3555
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Kinetic analysis of the electrocatalytic reduction of H2O2 on electrodes modified with thin Prussian blue films was performed and a full set of kinetic parameters governing the rate of the electrocatalytic reaction was determined. Rate constant (kappa.k') for the catalytic reaction between H2O2 and the reduced form of Prussian blue incorporating interstitial Cs+ and K+ ions was calculated to be equal to 3.1.10(6) and 2.3.10(6) cm(3).mol(-1) s(-1), respectively. The diffusion coefficient of H2O2 and the apparent diffusion coefficient of electrons in the reduced form of Prussian blue were found to be kappa center dot D-S(H2O2) = 2.6.10(-7) cm(2)/s and D-e = 2.8.10(-12) cm(2)/s, respectively.
引用
收藏
页码：403 / 410
页数：8
相关论文
共 50 条
  • [41] An electrochemical study of H2O2 decomposition on single-phase γ-FeOOH films
    Fu, D.
    Zhang, X.
    Keech, P. G.
    Shoesmith, D. W.
    Wren, J. C.
    ELECTROCHIMICA ACTA, 2010, 55 (11) : 3787 - 3796
  • [42] Structure effects of self-assembled Prussian blue confined in highly organized mesoporous TiO2 on the electrocatalytic properties towards H2O2 detection
    Gaitan, Martin
    Goncales, Vinicius R.
    Soler-Illia, Galo J. A. A.
    Baraldo, Luis M.
    Cordoba de Torresi, Susana I.
    BIOSENSORS & BIOELECTRONICS, 2010, 26 (02) : 890 - 893
  • [43] Prussian blue nanocubes on nitrobenzene-functionalized reduced graphene oxide and its application for H2O2 biosensing
    Wang, Li
    Ye, Yinjian
    Lu, Xingping
    Wu, Yi
    Sun, Lanlan
    Tan, Hongliang
    Xu, Fugang
    Song, Yonghai
    ELECTROCHIMICA ACTA, 2013, 114 : 223 - 232
  • [44] Electrochemical sensor based on Prussian blue nanorods and gold nanochains for the determination of H2O2
    Shihong Chen
    Liping Ma
    Ruo Yuan
    Yaqin Chai
    Yun Xiang
    Chengyan Wang
    European Food Research and Technology, 2011, 232 : 87 - 95
  • [45] A quantitative colorimetric assay of H2O2 and glucose using silver nanoparticles induced by H2O2 and UV
    Zhang, Yu
    Zhang, Yan-Jun
    Xia, Xiao-Dong
    Hou, Xiao-Qi
    Feng, Cheng-Ting
    Wang, Jian-Xiu
    Deng, Liu
    CHINESE CHEMICAL LETTERS, 2013, 24 (12) : 1053 - 1058
  • [46] Electrochemical sensor based on Prussian blue nanorods and gold nanochains for the determination of H2O2
    Chen, Shihong
    Ma, Liping
    Yuan, Ruo
    Chai, Yaqin
    Xiang, Yun
    Wang, Chengyan
    EUROPEAN FOOD RESEARCH AND TECHNOLOGY, 2011, 232 (01) : 87 - 95
  • [47] Analysis of the Toxicity of Phenol Solutions Treated with H2O2/UV and H2O2/Fe Oxidative Systems
    De Luis, A. M.
    Lombrana, J. I.
    Menendez, A.
    Sanz, J.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (04) : 1928 - 1937
  • [48] H2O2 Determination by a Biosensor Based on Hemoglobin
    Sezgintuerk, Mustafa Kemal
    Dinckaya, Erhan
    PREPARATIVE BIOCHEMISTRY & BIOTECHNOLOGY, 2009, 39 (01) : 1 - 10
  • [49] Efficiency and energy requirements for the transformation of organic micropollutants by ozone, O3/H2O2 and UV/H2O2
    Katsoyiannis, Ioannis A.
    Canonica, Silvio
    von Gunten, Urs
    WATER RESEARCH, 2011, 45 (13) : 3811 - 3822
  • [50] Electrocatalytic activity of LaNiO3 toward H2O2 reduction reaction: Minimization of oxygen evolution
    Amirfakhri, Seyed Javad
    Meunier, Jean-Luc
    Berk, Dimitrios
    JOURNAL OF POWER SOURCES, 2014, 272 : 248 - 258
12345