Unexpected formation of 4-methyl-1-vinyl-6-carboline in the reaction of 3-acetylindole oxime with acetylene

被引：10

作者：

Trofimov, Boris A. ^{[1
]}

Schmidt, Elena Yu. ^{[1
]}

Mikhaleva, Albina I. ^{[1
]}

Zorina, Nadezhda V. ^{[1
]}

Ushakov, Igor A. ^{[1
]}

Afonin, Andrey V. ^{[1
]}

Vasil'tsov, Alexander M. ^{[1
]}

机构：

[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia

来源：

MENDELEEV COMMUNICATIONS | 2007年 / 17卷 / 01期

关键词：

D O I：

10.1016/j.mencom.2007.01.016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3-Acetylindole oxime reacts with acetylene (KOH/DMSO, 120 degrees C, 1 h, 20-25 atm) to unexpectedly give 4-methyl-1-vinyl-delta-carboline 2 in 40% yield along with minor product 1-vinyl-3-(1'-vinyl-2'-pyrrolyl)indole 3 (6%).

引用

页码：40 / 42

页数：3

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