Cyclopropane formation via a simple barbier reaction in DMF

被引：0

作者：

Oudeyer, S ^{[1
]}

Aaziz, A ^{[1
]}

Léonel, E ^{[1
]}

Paugam, JP ^{[1
]}

Nédélec, JY ^{[1
]}

机构：

[1] Univ Paris 12, Lab Electrochim Catalyse & Synthese Organ, UMR 7582, CNRS, F-94320 Thiais, France

来源：

SYNLETT | 2003年 / 04期

关键词：

cyclopropanation; activated olefins; alpha-halomagnesium; reagents; Barbier reaction; carbenoids;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyclopropanes are prepared in good yields via magnesium activation of polyhalomethyl compounds (dichlorodiphenyl-methane, methyl trichloroacetate, alpha,alpha,alpha-trichlorotoluene, benzal chloride, benzal bromide) in the presence of activated olefins in DMF.

引用

页码：485 / 488

页数：4

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