Chemical approaches to semiconductor nanocrystals

被引：116

作者：

Brus, L ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1998年 / 59卷 / 04期

关键词：

nanostructures; chemical synthesis; high pressure;

D O I：

10.1016/S0022-3697(97)00201-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

I discuss the chemistry and physics of semiconductor nanocrystals. Various physical size regimes are outlined in both spectroscopic and kinetic properties. There is a solvation effect on electron transport kinetics due to the electric field of the moving carrier. The importance of chemical synthesis is emphasized with regard to both single nanocrystals, and self-assembled 'supercrystals' of nanocrystals. The potential metastability of nanocrystals at standard temperature and pressure (STP)I in unusual crystal structures thermodynamically stable only at high pressure, is suggested. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：459 / 465

页数：7

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