The Synthesis of an Extra-Large-Pore Zeolite with Double Three-Ring Building Units and a Low Framework Density

被引:155
作者
Jiang, Jiuxing [1 ,2 ]
Jorda, Jose L. [1 ]
Diaz-Cabanas, Maria J. [1 ]
Yu, Jihong [2 ]
Corma, Avelino [1 ]
机构
[1] Univ Politecn Valencia, Inst Tecnol Quim, CSIC, Valencia 46022, Spain
[2] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
关键词
high-throughput screening; microporous materials; structure elucidation; synthesis design; zeolites; PURE POLYMORPH-C; MOLECULAR-SIEVE; DESIGN;
D O I
10.1002/anie.201001506
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) The great wide open: High-throughput techniques have allowed an extra-largepore zeolite to be obtained that has an 18×12×12 ring pore system. This material (see picture) has the lowest framework density for a silica-based fully-connected zeolite, and is the first example with double three-ring units in its framework. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4986 / 4988
页数:3
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