Mixed-valence Li/Fe-based metal-organic frameworks with both reversible redox and sorption properties

被引：575
|
作者：
Ferey, Gerard
Millange, Franck
Morcrette, Mathieu
Serre, Christian
Doublet, Marie-Liesse
Greneche, Jean-Marc
Tarascon, Jean-Marie
机构：
[1] Univ Picardie, LRCS CNRS 6007, F-80039 Amiens, France
[2] Univ Versailles, UMR 8180, Inst Lavoisier, F-78035 Versailles, France
[3] Univ Montpellier 2, LSDSMS CNRS 5636, F-34095 Montpellier, France
[4] Univ Maine, LPEC CNRS 6087, F-72085 Le Mans, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 18期
关键词：
lithium; microporous materials; Mossbauer spectroscopy; organic-inorganic hybrid composites; X-ray diffraction;
D O I：
10.1002/anie.200605163
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
There's more to LiFe: When used as an electrode in a lithium half cell, the metal-organic framework [LixFeII xFe III 1-x(OH)0.8-F0.2L] (L = O 2CC6H4CO2) shows a reversible redox process around 3.0 V versus Li+/ Li0 with interesting capacity retention and rate capability (see voltage profile for a [Li xFe(OH)0.8F0.2L] half cell; inset: representation of lithium insertion upon oxidation to Li+). (Graph Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：3259 / 3263
页数：5
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