Mixed-valence Li/Fe-based metal-organic frameworks with both reversible redox and sorption properties

被引：581
作者：
Ferey, Gerard
Millange, Franck
Morcrette, Mathieu
Serre, Christian
Doublet, Marie-Liesse
Greneche, Jean-Marc
Tarascon, Jean-Marie
机构：
[1] Univ Picardie, LRCS CNRS 6007, F-80039 Amiens, France
[2] Univ Versailles, UMR 8180, Inst Lavoisier, F-78035 Versailles, France
[3] Univ Montpellier 2, LSDSMS CNRS 5636, F-34095 Montpellier, France
[4] Univ Maine, LPEC CNRS 6087, F-72085 Le Mans, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 18期
关键词：
lithium; microporous materials; Mossbauer spectroscopy; organic-inorganic hybrid composites; X-ray diffraction;
D O I：
10.1002/anie.200605163
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
There's more to LiFe: When used as an electrode in a lithium half cell, the metal-organic framework [LixFeII xFe III 1-x(OH)0.8-F0.2L] (L = O 2CC6H4CO2) shows a reversible redox process around 3.0 V versus Li+/ Li0 with interesting capacity retention and rate capability (see voltage profile for a [Li xFe(OH)0.8F0.2L] half cell; inset: representation of lithium insertion upon oxidation to Li+). (Graph Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：3259 / 3263
页数：5
相关论文
共 25 条
[1]  
Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO
[2]  
2-Y
[3]  
Barthelet K., 2002, ANGEW CHEM, V114, P291, DOI DOI 10.1002/1521-3757(20020118)114:2<291:AID-ANGE291>3.0.CO
[4]  
2-I
[5]   Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47 [J].
Bourrelly, S ;
Llewellyn, PL ;
Serre, C ;
Millange, F ;
Loiseau, T ;
Férey, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) :13519-13521
[6]  
Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO
[7]  
2-U
[8]  
Cheng C. Y., 2003, ANGEW CHEM, V115, P1981
[9]   NCHU-3: A crystalline inorganic-organic hybrid molecular sieve with extra-large cages [J].
Cheng, CY ;
Fu, SJ ;
Yang, CJ ;
Chen, WH ;
Lin, KJ ;
Lee, GH ;
Wang, Y .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (17) :1937-1940
[10]   A QUICK METHOD OF MEASURING THE CAPACITY VERSUS DISCHARGE RATE FOR A DUAL LITHIUM-ION INSERTION CELL UNDERGOING CYCLING [J].
DOYLE, M ;
NEWMAN, J ;
REIMERS, J .
JOURNAL OF POWER SOURCES, 1994, 52 (02) :211-216
123