A new zeolitic lithium aluminum imidazolate framework

被引:3
作者
Jiang, Guangshen [1 ,2 ]
Bon, Volodymyr [2 ]
Xu, Fei [1 ,2 ]
Garai, Bikash [2 ]
Zhang, En [2 ]
Senkovska, Irena [2 ]
Poetke, Stephanie [3 ]
Hippauf, Felix [3 ]
Hausdorf, Steffen [2 ]
Paasch, Silvia [4 ]
Brunner, Eike [4 ]
Wang, Hongqiang [1 ]
Kaskel, Stefan [2 ,3 ]
机构
[1] Northwestern Polytech Univ, State Key Lab Solidificat Proc, Sch Mat Sci & Engn, Shaanxi Joint Lab Graphene NPU, Xian 710072, Peoples R China
[2] Tech Univ Dresden, Dept Inorgan Chem, Bergstr 66, D-01062 Dresden, Germany
[3] Fraunhofer Inst Mat & Beam Technol IWS, Winterbergstr 28, D-01277 Dresden, Germany
[4] Tech Univ Dresden, Dept Bioanalyt Chem, Bergstr 66, D-01062 Dresden, Germany
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC FRAMEWORK; THERMAL-STABILITY; GAS-ADSORPTION; ZIF-8; SEPARATION; MEMBRANES;
D O I
10.1039/d1dt01017d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An aliovalent mixed-metal framework DUT-174 [LiAl(2-methylimidazolate)(4)](n), isostructural to ZIF-8, was synthesized from lithium aluminum hydride (LiAlH4) and 2-methylimidazole (2-mImH) through dehydrogenation. Lithium and aluminum cations acting as alternating framework nodes are coordinated tetrahedrally by (2-mIm)(-). DUT-174 has a high specific surface area of 1149 m(2) g(-1) and CO2 uptake of 11.57 mmol g(-1) at 195 K.
引用
收藏
页码:7933 / 7937
页数:5
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