Covalent organic framework film protected zinc anode for highly stable rechargeable aqueous zinc-ion batteries

被引:169
作者
Zhao, Jing [1 ,2 ]
Ying, Yunpan [1 ]
Wang, Guiling [2 ]
Hu, Kedi [1 ]
Yuan, Yi Di [1 ]
Ye, Hualin [1 ]
Liu, Zhaolin [3 ]
Lee, Jim Yang [1 ]
Zhao, Dan [1 ]
机构
[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore
[2] Harbin Engn Univ, Dept Mat Sci & Engn, Key Lab Superlight Mat & Surface Technol, Minist Educ, Harbin 150001, Heilongjiang, Peoples R China
[3] ASTAR, Inst Mat Res & Engn, 2 Fusionopolis Way,08-03 Innovis, Singapore 138634, Singapore
基金
新加坡国家研究基金会;
关键词
Covalent organic frameworks; Zn-ion batteries; Zn deposition; Dendrites; Corrosion; SULFONIC-ACID GROUPS; CATHODE; CRYSTALLINE; CHALLENGES;
D O I
10.1016/j.ensm.2022.02.054
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Although aqueous zinc-ion batteries (ZIBs) have demonstrated great potential for large-scale energy storage, dendrite growth in the Zn metal anode leads to poor electrochemical stability and unsatisfactory cycling life, restricting widespread utilization of ZIBs. Herein, a zincophilic covalent organic framework (COF; TpPa-SO3H) film is fabricated via interfacial reaction to stabilize the Zn anode (TpPa-SO3H@Zn-foil). The sulfonic acid groups on the TpPa-SO3H film coordinate with Zn2+ ions and regulate the uniform deposition of Zn2+ ions to inhibit the dendrite formation. Additionally, the TpPa-SO3H can release abundant protons (H (+)) and achieve a dynamic equilibrium with OH -, thereby adjusting the desolvation of [Zn(H2O)(6)](2+) to prevent secondary reactions. This work demonstrates that COF film-coated Zn anodes are a family of promising electrode candidates and provides inspiration to other fields of batteries, such as the material design for separator and electrolyte.
引用
收藏
页码:82 / 89
页数:8
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