Treatment of polluted river sediment by electrochemical oxidation: Changes of hydrophilicity and acute cytotoxicity of dissolved organic matter

River sediment is the main internal pollution source of water body. This study evaluated the feasibility of electrochemical oxidation (EO) for polluted river sediment treatment. The hydrophilic and acute cytotoxicity (ACT) of dissolved organic matter (DOM) during electrolysis were mainly investigated. Meanwhile, the behavior of sediment evolution was also characterized. The results showed that the EO process was feasible for the treatment of polluted river sediment. The COD removal efficiency of polluted river sediment can achieve to 40.1% when the current density was 50 mA cm(-2) with the chloride ion of 3000 mg L-1 and the initial pH of 8.5. The hydrophilicity of sediment DOM decreased with the decreasing molecule weight of humic-like substances, polar groups and the formation of aromatic aldehydes such as benzaldehyde. In this process, The ACT of sediment DOM can be reduced by the removal of aromatic compounds. In the process of electrolysis, the sediment particles were smaller than before, the dehydration was enhanced, and the crystal type tended to be stable, which was conducive to the utilization of resources. Therefore, EO method is a feasible alternative for the treatment of polluted river sediment. (C) 2019 Elsevier Ltd. All rights reserved.