3D-Printed Organic-Ceramic Complex Hybrid Structures with High Silica Content

被引:64
作者
Shukrun, Efrat [1 ]
Cooperstein, Ido [1 ]
Magdassi, Shlomo [1 ]
机构
[1] Hebrew Univ Jerusalem, Inst Chem, Casali Ctr Appl Chem, Ctr Nanosci & Nanotechnol, IL-9190401 Jerusalem, Israel
来源
ADVANCED SCIENCE | 2018年 / 5卷 / 08期
基金
新加坡国家研究基金会;
关键词
3D printing; digital light processing; hybrid organic-ceramic inks; sol-gel; UV curable materials; SOL-GEL PROCESS; SI-ALKOXIDES; POLYMERS; TECHNOLOGY; GLASSES;
D O I
10.1002/advs.201800061
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hybrid organic-inorganic sol gel inks that can undergo both condensation and radical polymerization are developed, enabling fabrication of complex objects by additive manufacturing technology, yielding 3D objects with superior properties. The 3D objects have very high silica content and are printed by digital light processing commercial printers. The printed lightweight objects are characterized by excellent mechanical strength compared to currently used high-performance polymers (139 MPa), very high stability at elevated temperatures (heat deflection temperature >270 degrees C), high transparency (89%), and lack of cracks, with glossiness similar to silica glasses. The new inks fill the gap in additive manufacturing of objects composed of ceramics only and organic materials only, thus enabling harnessing the advantages of both worlds of materials.
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页数:7
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