Low-dimensional compounds containing cyano groups.: VII.: (Dicyanamido-κN1)bis(1,10-phenanthroline-κ2N,N′)copper(II) trifluoromethanesulfonate

被引：5
作者：
Potocnák, I
Burcák, M
Wagner, C
Jäger, L
机构：
[1] Safarik Univ, Dept Inorgan Chem, Fac Sci, SK-04154 Kosice, Slovakia
[2] Univ Halle Wittenberg, Inst Inorgan Chem, D-06120 Halle An Der Saale, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2003年 / 59卷
关键词：
D O I：
10.1107/S0108270103010187
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Cu(C2N3)(C12H8N2)(2)](CF3SO3), is formed by discrete [Cu(phen)(2){N(CN)(2))}](+) complex cations (phen is 1,10-phenanthroline) and uncoordinated CF3SO3- anions. The Cu centre is five-coordinated in the form of a distorted trigonal bipyramid to two phen molecules and one dicyanamide ligand, which is coordinated through one nitrile N atom in the equatorial plane at a distance of 1.990 (2) Angstrom. The two axial Cu-N distances are similar (mean 1.993 Angstrom) and are substantially shorter than the two equatorial Cu-N bonds (mean 2.125 Angstrom).
引用
收藏
页码：M252 / M254
页数：3
相关论文
共 50 条
  • [21] Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)
    Ha, Kwang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M38 - U471
  • [22] Dibromidobis(1,10-phenanthroline-κ2N,N′)cadmium(II)
    Sun, Yu-Hui
    Luo, Shu-Fen
    Zhang, Xiu-Zhi
    Du, Zi-Yi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M708 - U224
  • [23] (Formato-κO)bis(1,10-phenanthroline-κ2N,N′)copper(II) formate hexahydrate
    Xu, Wei
    Lin, Jian-Li
    Xie, Hong-Zhen
    Zhang, Ming
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1496 - U139
  • [24] Diaquabis(1,10-phenanthroline-κ2N,N′)manganese(II) thiodiglycolate bis(1,10-phenanthroline-κ2N,N′)(thiodiglycolato-κ2O,O′)manganese(II) tridecahydrate
    Marek, J
    Trávnícek, Z
    Kopel, P
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 : M429 - M431
  • [25] (2-Hydroxyacetato-κO1)bis(1,10-phenanthroline-κ2N,N′)copper(II) nitrate
    Kong, Ya-Jie
    Yuan, Zhuang-Dong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M592 - U808
  • [26] Aqua(dicyanamido-κN1)(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(nitrato-κ2O,O′)cobalt(II)-2,9-dimethyl-1,10-phenanthroline-water (2/1/2)
    Cui, Feng-Hua
    Zhao, Pei-Zheng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1341 - U378
  • [27] (1,10-Phenanthroline-κ2N,N′)(triphenylphosphine-κP)silver(I) trifluoromethanesulfonate
    Wu, Jie-Qiang
    Jin, Qiong-Hua
    Hu, Ke-Yi
    Zhang, Cun-Lin
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1096 - U782
  • [28] Aquabis(dichloroacetato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)
    Liu, Yaru
    Ning, Jianzhong
    Sun, Junshan
    Zhang, Chuan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M113 - U1146
  • [29] Bis[nitratobis(pentafluorobenzoato)(1,10-phenanthrofine-κ2N,N′)manganese(II) dinitratobis(1,10-phenanthroline-κ2N,N′)manganese(II)
    Zhang, Xiangdong
    Ge, Chunhua
    Zhang, Xiaoyan
    Guo, Ya'nan
    Liu, Qitao
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M2237 - U1906
  • [30] Tris(1,10-phenanthroline-κ2N,N′)cobalt(III) tris(trifluoromethanesulfonate) dihydrate
    Hanauer, Matthias
    Neshat, Abdollah
    Bigioni, Terry P.
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2008, 64 : M111 - M113
12345