Low-dimensional compounds containing cyano groups.: VII.: (Dicyanamido-κN1)bis(1,10-phenanthroline-κ2N,N′)copper(II) trifluoromethanesulfonate

被引：5
|
作者：
Potocnák, I
Burcák, M
Wagner, C
Jäger, L
机构：
[1] Safarik Univ, Dept Inorgan Chem, Fac Sci, SK-04154 Kosice, Slovakia
[2] Univ Halle Wittenberg, Inst Inorgan Chem, D-06120 Halle An Der Saale, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2003年 / 59卷
关键词：
D O I：
10.1107/S0108270103010187
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Cu(C2N3)(C12H8N2)(2)](CF3SO3), is formed by discrete [Cu(phen)(2){N(CN)(2))}](+) complex cations (phen is 1,10-phenanthroline) and uncoordinated CF3SO3- anions. The Cu centre is five-coordinated in the form of a distorted trigonal bipyramid to two phen molecules and one dicyanamide ligand, which is coordinated through one nitrile N atom in the equatorial plane at a distance of 1.990 (2) Angstrom. The two axial Cu-N distances are similar (mean 1.993 Angstrom) and are substantially shorter than the two equatorial Cu-N bonds (mean 2.125 Angstrom).
引用
收藏
页码：M252 / M254
页数：3
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