Facile synthesis of Li1.2Mn0.54Co0.13Ni0.13O2 porous fiber as cathode material for lithium ion batteries

被引:8
作者
Yang, Chaofan [1 ]
Han, Shichao [1 ]
Huang, Junjie [1 ]
Qian, Minle [1 ]
机构
[1] Shaoxing Univ, Coll Chem & Chem Engn, Shaoxing 312000, Peoples R China
关键词
Inorganic compounds; Nanostructures; Electrochemical properties; Heat treatment; ELECTROCHEMICAL PROPERTIES; LAYERED OXIDE; PERFORMANCE; MICROSPHERES; NANOWIRES; LIMN2O4; MN; NI; CO;
D O I
10.1016/j.matchemphys.2014.11.029
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Li1.2Mn0.54Co0.13Ni0.13O2 is synthesized by the means of mixing cotton with a solution, which contains Li+, Mn2+, Ni2+ and Co2+. XRD spectrum indicates Li1.2Mn0.54Co0.13Ni0.13O2 is consisted of monoclinic phase (C2/m) and a-NaFeO2 phase (R-3m). SEM image shows Li1.2Mn0.54Co0.13Ni0.13O2 material has a porous fiber structure. TEM image presents the constructing particles have an average diameter of about 100 nm. This porous fiber material presents excellent electrochemical performance, can deliver a capacity of 250.3 mAh g(-1) at 25 mA g(-1) (0.1 C), and can be charged and discharged at 1250 mA g(-1) (5 C) with the stable capacity of 110.3 mAh g(-1) for 100 cycles. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:695 / 700
页数:6
相关论文
共 29 条
  • [1] Demonstrating oxygen loss and associated structural reorganization in the lithium battery cathode Li[Ni0.2Li0.2Mn0.6]O2
    Armstrong, A. Robert
    Holzapfel, Michael
    Novak, Petr
    Johnson, Christopher S.
    Kang, Sun-Ho
    Thackeray, Michael M.
    Bruce, Peter G.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (26) : 8694 - 8698
  • [2] Correlating Structural Changes and Gas Evolution during the Thermal Decomposition of Charged LixNi0.8Co0.15Al0.05O2 Cathode Materials
    Bak, Seong-Min
    Nam, Kyung-Wan
    Chang, Wonyoung
    Yu, Xiqian
    Hu, Enyuan
    Hwang, Sooyeon
    Stach, Eric A.
    Kim, Kwang-Bum
    Chung, Kyung Yoon
    Yang, Xiao-Qing
    [J]. CHEMISTRY OF MATERIALS, 2013, 25 (03) : 337 - 351
  • [3] Evolutions of Li1.2Mn0.61Ni0.18Mg0.01O2 during the Initial Charge/Discharge Cycle Studied by Advanced Electron Microscopy
    Boulineau, Adrien
    Simonin, Loic
    Colin, Jean-Francois
    Canevet, Emmanuel
    Daniel, Lise
    Patoux, Sebastien
    [J]. CHEMISTRY OF MATERIALS, 2012, 24 (18) : 3558 - 3566
  • [4] Scalable LiCoO2 Nanoparticle Fibers for High Power Lithium Battery Cathodes
    Choi, Dong In
    Han, Gi-Beom
    Lee, Dong Jin
    Park, Jung-Ki
    Choi, Jang Wook
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (10) : A1150 - A1154
  • [5] Porous LiMn2O4 microspheres as durable high power cathode materials for lithium ion batteries
    Deng, Yuanfu
    Zhou, Yubo
    Shi, Zhicong
    Zhou, Xue
    Quan, Xie
    Chen, Guohua
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (28) : 8170 - 8177
  • [6] Critical Role of Oxygen Evolved from Layered Li-Excess Metal Oxides in Lithium Rechargeable Batteries
    Hong, Jihyun
    Lim, Hee-Dae
    Lee, Minah
    Kim, Sung-Wook
    Kim, Haegyeom
    Oh, Song-Taek
    Chung, Geun-Chang
    Kang, Kisuk
    [J]. CHEMISTRY OF MATERIALS, 2012, 24 (14) : 2692 - 2697
  • [7] Synthesis of LiNi0.5Mn1.5O4 and 0.5Li2MnO3-0.5LiNi1/3 Co1/3Mn1/3O2 hollow nanowires by electrospinning
    Hosono, Eiji
    Saito, Tatsuya
    Hoshino, Junichi
    Mizuno, Yoshifumi
    Okubo, Masashi
    Asakura, Daisuke
    Kagesawa, Koichi
    Nishio-Hamane, Daisuke
    Kudo, Tetsuichi
    Zhou, Haoshen
    [J]. CRYSTENGCOMM, 2013, 15 (14): : 2592 - 2597
  • [8] Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of a Solid Solution
    Jarvis, Karalee A.
    Deng, Zengqiang
    Allard, Lawrence F.
    Manthiram, Arumugam
    Ferreira, Paulo J.
    [J]. CHEMISTRY OF MATERIALS, 2011, 23 (16) : 3614 - 3621
  • [9] Hollow 0.3Li2MnO3•0.7LiNi0.5Mn0.5O2 microspheres as a high-performance cathode material for lithium-ion batteries
    Jiang, Yan
    Yang, Ze
    Luo, Wei
    Hu, Xianluo
    Huang, Yunhui
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (08) : 2954 - 2960
  • [10] Facile synthesis of mesoporous 0.4Li2MnO3•0.6LiNi2/3Mn1/3O2 foams with superior performance for lithium-ion batteries
    Jiang, Yan
    Yang, Ze
    Luo, Wei
    Hu, Xian-Luo
    Zhang, Wu-Xing
    Huang, Yun-Hui
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (30) : 14964 - 14969