Facile synthesis of Li1.2Mn0.54Co0.13Ni0.13O2 porous fiber as cathode material for lithium ion batteries

被引:8
作者
Yang, Chaofan [1 ]
Han, Shichao [1 ]
Huang, Junjie [1 ]
Qian, Minle [1 ]
机构
[1] Shaoxing Univ, Coll Chem & Chem Engn, Shaoxing 312000, Peoples R China
关键词
Inorganic compounds; Nanostructures; Electrochemical properties; Heat treatment; ELECTROCHEMICAL PROPERTIES; LAYERED OXIDE; PERFORMANCE; MICROSPHERES; NANOWIRES; LIMN2O4; MN; NI; CO;
D O I
10.1016/j.matchemphys.2014.11.029
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Li1.2Mn0.54Co0.13Ni0.13O2 is synthesized by the means of mixing cotton with a solution, which contains Li+, Mn2+, Ni2+ and Co2+. XRD spectrum indicates Li1.2Mn0.54Co0.13Ni0.13O2 is consisted of monoclinic phase (C2/m) and a-NaFeO2 phase (R-3m). SEM image shows Li1.2Mn0.54Co0.13Ni0.13O2 material has a porous fiber structure. TEM image presents the constructing particles have an average diameter of about 100 nm. This porous fiber material presents excellent electrochemical performance, can deliver a capacity of 250.3 mAh g(-1) at 25 mA g(-1) (0.1 C), and can be charged and discharged at 1250 mA g(-1) (5 C) with the stable capacity of 110.3 mAh g(-1) for 100 cycles. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:695 / 700
页数:6
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