Cobalt sulfides as efficient catalyst towards oxygen reduction reactions

被引：29

作者：

Yao, Shuo ^{[1
,2
]}

Huang, Taizhong ^{[1
]}

Fang, Hengyi ^{[1
]}

Yu, Jiemei ^{[1
]}

Meganathan, Mayilvel Dinesh ^{[1
]}

Cui, Zhaoxin ^{[1
]}

Yuan, Xianxia ^{[2
]}

机构：

[1] Univ Jinan, Sch Chem & Chem Engn, Shandong Prov Key Lab Fluorine Chem & Chem Mat, Jinan 250022, Peoples R China

[2] Shanghai Jiao Tong Univ, Dept Chem Engn, Shanghai 200240, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2020年 / 31卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Oxygen reduction reaction; Catalysts; Cobalt sulfides; Reduced graphene oxide; Catalytic performance; NITROGEN-DOPED CARBON; BIFUNCTIONAL ELECTROCATALYST; POROUS CARBON; GRAPHENE; NANOPARTICLES; GRAPHITE; SUPPORT;

D O I：

10.1016/j.cclet.2019.04.069

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Developing low-cost and high performance catalysts to replace precious metal based catalysts for oxygen reduction reaction (ORR) is one of the most feasible ways to promote the commercial application of fuel cells. In this work, flower-like CoS and octahedral CoS2 are synthesized by a facile one-pot hydrothermal method without any adjunction of surfactants or follow-up thermolysis, their catalytic performance towards ORR in alkaline electrolyte are comparatively investigated. The results reveal that CoS2 outperforms CoS owing to the higher electron density around S-S bond of S-2(2-) in the crystal structure, which promotes the adsorption of oxygen on catalyst surface and facilitates the breakage of O-O bond in oxygen, leading to direct 4-electron transfer ORR. When CoS2 particles are dispersed on the surface of rGO with large surface area, their ORR performance could be further improved. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

引用

页码：530 / 534

页数：5

共 39 条

[1] Rudimentary simple, single step fabrication of nano-flakes like AgCd alloy electro-catalyst for oxygen reduction reaction in alkaline fuel cell [J].