Synthesis of stereoisomers of p-tert-butylthiacalix[4]arenes tetrasubstituted at the lower rim containing secondary amide groups and their complexation with a number of singly charged anions

被引：13
|
作者：
Zhukov, A. Yu. [1 ]
Fink, T. A. [1 ]
Stoikov, I. I. [1 ]
Antipin, I. S. [1 ]
机构：
[1] Kazan VI Lenin State Univ, AM Butlerov Chem Inst, Kazan 420008, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 05期
基金：
俄罗斯基础研究基金会;
关键词：
molecular recognition; thiacalixarenes; amides; complexation; anions; CHEMISTRY; RECEPTOR;
D O I：
10.1007/s11172-009-0129-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ability of new synthetic receptors, i.e., p-tert-butylthiacalix[4]arenes tetrasubstituted at the lower rim and containing secondary amide groups to form complexes with a number of spherical (F-, Cl-, Br-, I-), Y-shaped (MeCOO-), trigonal (NO3 (-)), and tetrahedral (H2POO4 (-)) anions has been studied. It was shown that the nature of substituents on the nitrogen atom of the amide groups and configuration of the macrocycle affect the stability constant values of the forming complexes.
引用
收藏
页码：1007 / 1014
页数：8
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