Dibromido(4′-phenyl-2,2′:6′,2"-terpyridyl)copper(II) hemihydrate

被引：4

作者：

Ma, Zhen ^{[1
,2
]}

Bi, Chunyan ^{[1
]}

Ran, Guangyou ^{[1
]}

Wu, Zhang ^{[1
]}

Liu, Baoqing ^{[1
]}

Hu, Miao ^{[1
]}

Xing, Yanpeng ^{[1
]}

机构：

[1] Guangxi Univ, Sch Chem & Chem Engn, Guangxi 530004, Peoples R China

[2] Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

COMPLEXES; CRYSTAL;

D O I：

10.1107/S1600536810010585

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title Cu(II) complex, [CuBr(2)(C(21)H(15)N(3))]center dot 0.5H(2)O, was obtained by the hydrothermal reaction of copper(II) bromide, 4'-phenyl-2,2':6',2 ''-terpyridyl (4'-Ph-terpy or L) and sodium citrate in water in 31% yield. There are two unique complex molecules and a water molecule in the asymmetric unit. The Cu(II) cation is ligated by three N atoms of L and two bromide anions, forming an irregular CuN(3)Br(2) polyhedron with a distorted square-pyramidal coordination geometry. In the crystal structure, O-H center dot center dot center dot Br hydrogen bonds link the molecules in a three-dimensional network.

引用

页码：M465 / U1195

页数：15

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