Dibromido(4′-phenyl-2,2′:6′,2"-terpyridyl)copper(II) hemihydrate

被引：4
|
作者：
Ma, Zhen [1 ,2 ]
Bi, Chunyan [1 ]
Ran, Guangyou [1 ]
Wu, Zhang [1 ]
Liu, Baoqing [1 ]
Hu, Miao [1 ]
Xing, Yanpeng [1 ]
机构：
[1] Guangxi Univ, Sch Chem & Chem Engn, Guangxi 530004, Peoples R China
[2] Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
COMPLEXES; CRYSTAL;
D O I：
10.1107/S1600536810010585
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title Cu(II) complex, [CuBr(2)(C(21)H(15)N(3))]center dot 0.5H(2)O, was obtained by the hydrothermal reaction of copper(II) bromide, 4'-phenyl-2,2':6',2 ''-terpyridyl (4'-Ph-terpy or L) and sodium citrate in water in 31% yield. There are two unique complex molecules and a water molecule in the asymmetric unit. The Cu(II) cation is ligated by three N atoms of L and two bromide anions, forming an irregular CuN(3)Br(2) polyhedron with a distorted square-pyramidal coordination geometry. In the crystal structure, O-H center dot center dot center dot Br hydrogen bonds link the molecules in a three-dimensional network.
引用
收藏
页码：M465 / U1195
页数：15
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