Structure and spectral properties of the silver-containing high-silica glasses

被引:4
作者
Girsova, M. A. [1 ]
Golovina, G. F. [1 ]
Anfimova, I. N. [1 ]
Arsent'ev, M. Yu [2 ]
Antropova, T. V. [1 ]
机构
[1] RAS, Grebenshchikov Inst Silicate Chem, Lab Phys Chem Glass, St Petersburg 199034, Russia
[2] RAS, Grebenshchikov Inst Silicate Chem, Lab Res Nanostruct, St Petersburg 199034, Russia
来源
3RD INTERNATIONAL SCHOOL AND CONFERENCE ON OPTOELECTRONICS, PHOTONICS, ENGINEERING AND NANOSTRUCTURES (SAINT PETERSBURG OPEN 2016) | 2016年 / 741卷
关键词
OPTICAL-PROPERTIES; FT-IR; RAMAN;
D O I
10.1088/1742-6596/741/1/012144
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Silver-containing high-silica glasses were synthesized by an impregnation of the silica porous glasses (PGs) first with AgNO3 aqueous solution (with or without the presence of the sensitizers, such as Cu(NO3)(2) or Ce(NO3)(3)), next in the mixed halide salt (NH4Cl, KBr, KI) solution. Then some part of the samples was sintered at the temperatures from 850 to 900 degrees C up to closing of the pores. The structure of glasses was studied by UV-VIS-NIR and IR spectroscopy and X-ray diffraction (XRD) techniques. According to XRD data the silver-containing high-silica glasses contain the AgBr, AgI, Ag3PO4, (CuBr)(0.75)(CuI)(0.25) phases. IR spectra confirmed B-O-B, Si-O-Si, P-O-P, O-P-O, O-B-O bonds, (PO4)(3)(-) and P-O-groups in glasses.
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页数:5
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