Effect of imidazolium-based ionic liquid on vapor liquid equilibria of 2-propanol + acetonitrile binary system at 101.3 kPa

被引：13

作者：

Zhu, Wei ^{[1
]}

Qing, Li ^{[1
]}

Liu, Bing ^{[1
]}

Cai, Xinbing ^{[2
]}

Fan, Zenglu ^{[2
]}

机构：

[1] Xian Polytech Univ, Coll Environm & Chem Engn, Xian 710048, Peoples R China

[2] Xian Polytech Univ, Text & Mat Coll, Xian 710048, Peoples R China

来源：

FLUID PHASE EQUILIBRIA | 2016年 / 409卷

关键词：

Vapor-liquid equilibrium; 2-propanol; Acetonitrile; 1-ethyl-3-methylimidazolium; tetrafluoroborate; 1-butyl-3-methylimidazolium; EXTRACTIVE DISTILLATION; MIXTURES; METHANOL; ETHANOL; ACETONITRILE;

D O I：

10.1016/j.fluid.2015.10.035

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Vapor liquid equilibrium (VLE) data for one binary system (2-propanol + acetonitrile) and two ternary systems {2-propanol + acetonitrile + 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM][BF4]), 2-propanol + acetonitrile + 1-butyl-3- methylimidazolium tetrafluoroborate ([BMIM][BF4])} were determined at atmospheric pressure (101.3 kPa). It was found that the studied ionic liquids (ILs) both showed a salting-out effect, which leads to the elimination of the azeotropic point, and that the order of separation capacity for imidazolium-based ILs is [EMIM][BF4] > [BMIM][BF4]. All experimental data could be well correlated by nonrandom two-liquid (NRTL) model. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：383 / 387

页数：5

共 21 条

[1] HYDROCARBON AZEOTROPES WITH ACETONITRILE [J].

BISHOP, RB ;

DENTON, WI .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1950, 42 (05) :883-885

[2] Isobaric vapor-liquid equilibrium for methanol plus dimethyl carbonate plus phosphoric-based ionic liquids [J].

Cai, Fufeng ;

Wu, Xinying ;

Chen, Chang ;

Chen, Xiaochun ;

Asumana, Charles ;

Haque, Md Razibul ;

Yu, Guangren .

FLUID PHASE EQUILIBRIA, 2013, 352 :47-53

[3] Vapor-liquid equilibria for tetrahydrofuran plus ethanol system containing three different ionic liquids at 101.3 kPa [J].

Cao, Ling ;

Liu, Panpan ;

Wang, Baohua ;

Li, Qunsheng .

FLUID PHASE EQUILIBRIA, 2014, 372 :49-55

[4]

Carl L. Y., 1999, Chemical properties handbook

[5]

Gmehling J., 1977, Chemistry Data Series, V1

[6] Recent developments in thermodynamics and thermophysics of non-aqueous mixtures containing ionic liquids. A review [J].

Heintz, A .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2005, 37 (06) :525-535

[7] Tailor-made ionic liquids [J].

Jork, C ;

Kristen, C ;

Pieraccini, D ;

Stark, A ;

Chiappe, C ;

Beste, YA ;

Arlt, W .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2005, 37 (06) :537-558

[8]

Klesele H., 1980, ANAL CHEM, V52, P2230

[9]

Lei Z., 2005, Special distillation processes

[10] Extractive distillation: A review [J].

Lei, ZG ;

Li, CY ;

Chen, BH .

SEPARATION AND PURIFICATION REVIEWS, 2003, 32 (02) :121-213

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