Phosphorus-Containing Flame Retardants from Biobased Chemicals and Their Application in Polyesters and Epoxy Resins

被引：72

作者：

Sag, Jacob ^{[1
]}

Goedderz, Daniela ^{[1
,2
]}

Kukla, Philipp ^{[1
]}

Greiner, Lara ^{[1
]}

Schoenberger, Frank ^{[1
]}

Doering, Manfred ^{[1
]}

机构：

[1] Fraunhofer Inst Struct Durabil & Syst Reliabil LB, D-64289 Darmstadt, Germany

[2] Tech Univ Darmstadt, Ernst Berl Inst Chem Engn & Macromol Sci, D-64287 Darmstadt, Germany

来源：

MOLECULES | 2019年 / 24卷 / 20期

关键词：

biobased polymers; polyester; epoxy resin; flame retardant; phosphorus-containing flame retardants; THERMAL-DEGRADATION BEHAVIOR; POLY(LACTIC ACID); BETA-CYCLODEXTRIN; RENEWABLE RESOURCES; PHYTIC ACID; BIOTECHNOLOGICAL PRODUCTION; MECHANICAL-PROPERTIES; COMBUSTION PROPERTIES; ALIPHATIC POLYESTERS; INCLUSION COMPLEX;

D O I：

10.3390/molecules24203746

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Phosphorus-containing flame retardants synthesized from renewable resources have had a lot of impact in recent years. This article outlines the synthesis, characterization and evaluation of these compounds in polyesters and epoxy resins. The different approaches used in producing biobased flame retardant polyesters and epoxy resins are reported. While for the polyesters biomass derived compounds usually are phosphorylated and melt blended with the polymer, biobased flame retardants for epoxy resins are directly incorporated into the polymer structure by a using a phosphorylated biobased monomer or curing agent. Evaluating the efficiency of the flame retardant composites is done by discussing results obtained from UL94 vertical burning, limiting oxygen index (LOI) and cone calorimetry tests. The review ends with an outlook on future development trends of biobased flame retardant systems for polyesters and epoxy resins.

引用

页数：31

共 185 条

[41]

De Carvalho JC, 2018, CHIM OGGI, V36, P56

[42] Synthesis and characterization of polyesters based on tartaric acid derivatives [J].

Dhamaniya, Sunil ;

Jacob, Josemon .

POLYMER, 2010, 51 (23) :5392-5399

[43]

Domenek S., 2011, Biopolymers: Biomedical and Environmental Applications, Vfirst, P183, DOI [10.1002/9781118164792.ch8, DOI 10.1002/9781118164792.CH8]

[44] Cardanol and Eugenol Based Flame Retardant Epoxy Monomers for Thermostable Networks [J].