Innovative solvent for two-phase catalysis - Ionic fluids

被引：30
作者：
Wasserscheid, P [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Tech Chem & Makromol Chem, D-52074 Aachen, Germany
来源：
CHEMIE IN UNSERER ZEIT | 2003年 / 37卷 / 01期
关键词：
MOLTEN-SALT; PHOSPHINE-LIGANDS; LIQUIDS; COMPLEXES; HYDROFORMYLATION; ELECTROCHEMISTRY; SPECTROSCOPY; DIMERIZATION; ALKENES;
D O I：
10.1002/ciuz.200390006
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ionic liquids are low melting salts which represent a new class of non-molecular, ionic solvents. By combining different cations and anions a large number of liquids with very different physical and chemical properties can be obtained. It is possible to optimize the ionic medium for a specific application by the careful choice of the ion combination. Ionic liquids are interesting substitutes for organic solvent in catalytic reactions for many reasons: Besides their non-volatile nature offering significant engineering advantages, the unusual solubility properties of these liquids enable new multiphasic catalytic reactions.
引用
收藏
页码：52 / 63
页数：12
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