Innovative solvent for two-phase catalysis - Ionic fluids

被引：30

作者：

Wasserscheid, P ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Tech Chem & Makromol Chem, D-52074 Aachen, Germany

来源：

CHEMIE IN UNSERER ZEIT | 2003年 / 37卷 / 01期

关键词：

MOLTEN-SALT; PHOSPHINE-LIGANDS; LIQUIDS; COMPLEXES; HYDROFORMYLATION; ELECTROCHEMISTRY; SPECTROSCOPY; DIMERIZATION; ALKENES;

D O I：

10.1002/ciuz.200390006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic liquids are low melting salts which represent a new class of non-molecular, ionic solvents. By combining different cations and anions a large number of liquids with very different physical and chemical properties can be obtained. It is possible to optimize the ionic medium for a specific application by the careful choice of the ion combination. Ionic liquids are interesting substitutes for organic solvent in catalytic reactions for many reasons: Besides their non-volatile nature offering significant engineering advantages, the unusual solubility properties of these liquids enable new multiphasic catalytic reactions.

引用

页码：52 / 63

页数：12

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