pH- and thermosensitive supramolecular assembling system:: Rapidly responsive properties of β-cyclodextrin-conjugated poly(ε-lysine)

被引：101

作者：

Choi, HS ^{[1
]}

Huh, KM ^{[1
]}

Ooya, T ^{[1
]}

Yui, N ^{[1
]}

机构：

[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 21期

关键词：

D O I：

10.1021/ja034149x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

β-Cyclodextrin-conjugated poly(ε-lysine) (β-CDPL) was synthesized as a novel polymeric host for constructing a smart supramolecular assembling system. Systematic studies on the inclusion complexation between the polymeric host with an α- or β-CD cavity and a model guest molecule provided evidence that dual cooperative interactions, specific host-guest interaction and intermolecular ionic interaction, played a dominant role in leading to a fast aggregation phenomenon. In addition, a rapid phase transition induced by the supramolecular assembly was observed reversibly in response to a small change in pH or temperature. Copyright © 2003 American Chemical Society.

引用

页码：6350 / 6351

页数：2

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