Hydrosilylation catalysed by a rhodium complex in a supercritical CO2/ionic liquid system

被引：28

作者：

Li, Jiayun ^{[1
,2
]}

Peng, Jiajian ^{[1
]}

Zhang, Guodong ^{[1
]}

Bai, Ying ^{[1
]}

Lai, Guoqiao ^{[1
]}

Li, Xiaonian ^{[2
]}

机构：

[1] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China

[2] Zhejiang Univ Technol, Resources & Environm Catalysis Inst, State Key Lab Breeding Base Green Chem Synth Tech, Hangzhou 310032, Zhejiang, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2010年 / 34卷 / 07期

关键词：

IONIC LIQUIDS; CARBON-DIOXIDE; ASYMMETRIC HYDROGENATION; CO2; HYDROFORMYLATION; EXTRACTION; MECHANISM;

D O I：

10.1039/c0nj00012d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrosilylation of alkenes in a supercritical CO2 (scCO(2))/ionic liquid (IL) system was investigated. Rh(PPh3)(3)Cl exhibited excellent catalytic activity and selectivity. (KOBu)-Bu-t was used as an additive, and no hydrogenation by-product (alkane) was detected in the scCO(2)/IL system. During hydrosilylation in the scCO(2)/IL system, the reactants were possibly transferred into the IL phase by scCO(2), in which the catalyst was dissolved. The products can be flushed with scCO(2) after the reaction and the catalyst/IL system reused.

引用

页码：1330 / 1334

页数：5

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