Analysis of sloping plateaux in alloys and intermetallic hydrides - I. Diagnostic features

被引:38
作者
Park, CN
Luo, SF
Flanagan, TB [1 ]
机构
[1] Univ Vermont, Mat Sci Program, Burlington, VT 05405 USA
[2] Chonnam Natl Univ, Dept Engn Met, Kwangju 500757, South Korea
关键词
sloping plateaux; alloy; intermetallic hydride;
D O I
10.1016/j.jallcom.2004.04.101
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Previous research has accounted for sloping plateaux by assuming Gaussian distributions of plateau pressures, or of the corresponding thermodynamic parameters, and then fitting the experimental degree of sloping by trial and error. In the present treatment a method is developed to utilize the experimental plateau sloping to determine the compositional distribution functions for an alloy or an intermetallic compound-hydride, A(1-x)-B-x-H where, due to inhomogeneity, x will deviate within the sample from its nominal value. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:203 / 207
页数:5
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